Postdoctoral Fellowship: MPS-Ascend: The Effects of Electronic Stucture and Coordination Enviornment on the Electrochemical Reduction of Carbon Dioxide in Single-Atom Catalysts

博士后奖学金:MPS-Ascend:电子结构和配位环境对单原子催化剂中二氧化碳电化学还原的影响

基本信息

  • 批准号:
    2316741
  • 负责人:
  • 金额:
    $ 30万
  • 依托单位:
  • 依托单位国家:
    美国
  • 项目类别:
    Fellowship Award
  • 财政年份:
    2023
  • 资助国家:
    美国
  • 起止时间:
    2023-07-01 至 2026-06-30
  • 项目状态:
    未结题

项目摘要

Mathew Ryan Espinosa is awarded an NSF Mathematical and Physical Sciences Ascending Postdoctoral Research Fellowship (NSF MPS-Ascend) to conduct a program of research and activities related to broaden participation by groups underrepresented in STEM. This fellowship to Dr. Ezpinosa supports the research project entitled “MPS-Ascend: The Effects of Electronic Structure and Coordination Environment on the Electrochemical Reduction of Carbon Dioxide in Single-Atom Catalysts” under the mentorship of a sponsoring scientist. The host institution for the fellowship is California Institute of Technology at Pasadena, CA, and the sponsoring scientist is Dr. Theodor Agapie.This proposal intends to investigate the fundamental factors influencing the selectivity and activity of heterogeneous single-atom catalysts in electrochemical CO2 reduction. The proposal will utilize electronically conjugated multi-metallic phenanthroline macrocyclic catalysts to understand the influence of the extended electronic structure of single-atom catalysts on the catalytic activity and selectivity of CO2 reduction to liquid products and fuels. The project will synthesize novel homogeneous mono- and multi-metallic systems where electronic structure and secondary coordination environment will be systematically varied and compared to the catalytic activity and selectivity. Successful implementation of this work may allow for developing single-atom catalysts involving electronically conjugated metal centers on a conducting surface for CO2 reduction to renewable commodity chemicals and fuels. The conversion of captured anthropogenic CO2 using electrochemical reduction would enable the production of renewable, carbon-neutral fuels and chemical feedstocks, displacing current unsustainable petrochemical sources. The PI intends to increase broadening participation of underrepresented groups in science by mentoring and providing opportunities to the next generation of scientists and participating in scientific outreach activities, scientific communications, and community service to inspire and inform local communities.This award reflects NSF's statutory mission and has been deemed worthy of support through evaluation using the Foundation's intellectual merit and broader impacts review criteria.
马修·瑞安·埃斯皮诺萨被授予NSF数学和物理科学上升博士后研究奖学金(NSF MPS-Ascend),以开展一项与扩大STEM中代表性不足群体的参与相关的研究和活动。这项给Ezpinosa博士的奖学金支持在一位赞助科学家的指导下开展的题为《MPS-Ascend:电子结构和配位环境对单原子催化剂中二氧化碳电化学还原的影响》的研究项目。这项研究的主办机构是加州帕萨迪纳的加州理工学院,发起科学家是Theodor Agapie博士。这项建议旨在研究影响多相单原子催化剂在电化学还原二氧化碳中的选择性和活性的基本因素。该提案将利用电子共轭的多金属邻菲咯啉大环催化剂来了解单原子催化剂的扩展电子结构对二氧化碳还原为液体产品和燃料的催化活性和选择性的影响。该项目将合成新型的均相单金属和多金属体系,其中电子结构和二次配位环境将发生系统的变化,并与催化活性和选择性进行比较。这项工作的成功实施可能有助于开发单原子催化剂,该催化剂包括导电表面上的电子共轭金属中心,用于将二氧化碳还原为可再生商品、化学品和燃料。利用电化学还原技术转化捕获的人为二氧化碳,将能够生产可再生的碳中性燃料和化学原料,取代目前不可持续的石化资源。PI打算通过指导和为下一代科学家提供机会,并参与科学推广活动、科学交流和社区服务来激励和告知当地社区,以增加未被充分代表的群体在科学领域的广泛参与。这一奖项反映了NSF的法定使命,并通过使用基金会的智力优势和更广泛的影响审查标准进行评估,被认为值得支持。

项目成果

期刊论文数量(0)
专著数量(0)
科研奖励数量(0)
会议论文数量(0)
专利数量(0)

数据更新时间:{{ journalArticles.updateTime }}

{{ item.title }}
{{ item.translation_title }}
  • DOI:
    {{ item.doi }}
  • 发表时间:
    {{ item.publish_year }}
  • 期刊:
  • 影响因子:
    {{ item.factor }}
  • 作者:
    {{ item.authors }}
  • 通讯作者:
    {{ item.author }}

数据更新时间:{{ journalArticles.updateTime }}

{{ item.title }}
  • 作者:
    {{ item.author }}

数据更新时间:{{ monograph.updateTime }}

{{ item.title }}
  • 作者:
    {{ item.author }}

数据更新时间:{{ sciAawards.updateTime }}

{{ item.title }}
  • 作者:
    {{ item.author }}

数据更新时间:{{ conferencePapers.updateTime }}

{{ item.title }}
  • 作者:
    {{ item.author }}

数据更新时间:{{ patent.updateTime }}

Matthew Espinosa其他文献

You are what you (are willing to) eat: Willingness to try new foods impacts perceptions of sexual unrestrictedness and desirability
  • DOI:
    10.1016/j.paid.2021.111082
  • 发表时间:
    2021-11-01
  • 期刊:
  • 影响因子:
  • 作者:
    Hannah K. Bradshaw;Summer Mengelkoch;Matthew Espinosa;Alex Darrell;Sarah E. Hill
  • 通讯作者:
    Sarah E. Hill
Tuuned in: use of an online contraceptive decision aid for women increases reproductive self-efficacy and knowledge; results of an experimental clinical trial
调整:使用在线避孕决策辅助工具可以提高女性的生殖自我效能和知识;
  • DOI:
    10.1186/s44247-023-00034-z
  • 发表时间:
    2023
  • 期刊:
  • 影响因子:
    0
  • 作者:
    Summer Mengelkoch;Matthew Espinosa;Stephen A. Butler;Laura Joigneau Prieto;Emma Russell;Chris Ramshaw;Shardi Nahavandi;Sarah E. Hill
  • 通讯作者:
    Sarah E. Hill

Matthew Espinosa的其他文献

{{ item.title }}
{{ item.translation_title }}
  • DOI:
    {{ item.doi }}
  • 发表时间:
    {{ item.publish_year }}
  • 期刊:
  • 影响因子:
    {{ item.factor }}
  • 作者:
    {{ item.authors }}
  • 通讯作者:
    {{ item.author }}

相似海外基金

Postdoctoral Fellowship: MPS-Ascend: Topological Enrichments in Enumerative Geometry
博士后奖学金:MPS-Ascend:枚举几何中的拓扑丰富
  • 批准号:
    2402099
  • 财政年份:
    2024
  • 资助金额:
    $ 30万
  • 项目类别:
    Fellowship Award
Postdoctoral Fellowship: MPS-Ascend: Quantifying Accelerated Reaction Kinetics in Microdroplets with pH-Jump and Mass Spectrometry: From Small Molecules to Proteins and Beyond
博士后奖学金:MPS-Ascend:利用 pH 跳跃和质谱定量微滴中的加速反应动力学:从小分子到蛋白质及其他
  • 批准号:
    2316167
  • 财政年份:
    2023
  • 资助金额:
    $ 30万
  • 项目类别:
    Fellowship Award
Postdoctoral Fellowship: MPS-Ascend: Understanding Fukaya categories through Homological Mirror Symmetry
博士后奖学金:MPS-Ascend:通过同调镜像对称理解深谷范畴
  • 批准号:
    2316538
  • 财政年份:
    2023
  • 资助金额:
    $ 30万
  • 项目类别:
    Fellowship Award
Postdoctoral Fellowship: MPS-Ascend: Coarse-Grained Modeling of Aggrecan- Mimetic Copolymers: Polymer Design and Architecture Effects on Structure and Phase Behavior
博士后奖学金:MPS-Ascend:聚集蛋白聚糖模拟共聚物的粗粒度建模:聚合物设计和结构对结构和相行为的影响
  • 批准号:
    2316666
  • 财政年份:
    2023
  • 资助金额:
    $ 30万
  • 项目类别:
    Fellowship Award
Postdoctoral Fellowship: MPS-Ascend: The Early Universe Laboratory: Primordial Phenomena as Probes of New Physics
博士后奖学金:MPS-Ascend:早期宇宙实验室:原始现象作为新物理学的探针
  • 批准号:
    2317018
  • 财政年份:
    2023
  • 资助金额:
    $ 30万
  • 项目类别:
    Fellowship Award
Postdoctoral Fellowship: MPS-Ascend: Advancing Mosquito-borne Disease Models with Distributed Delay Equations
博士后奖学金:MPS-Ascend:利用分布式延迟方程推进蚊媒疾病模型
  • 批准号:
    2316455
  • 财政年份:
    2023
  • 资助金额:
    $ 30万
  • 项目类别:
    Fellowship Award
Postdoctoral Fellowship: MPS-Ascend: Vortex-beam Spectroscopy of Type-II Superconductors in the THz Regime
博士后奖学金:MPS-Ascend:太赫兹体系中 II 型超导体的涡旋光束光谱
  • 批准号:
    2316535
  • 财政年份:
    2023
  • 资助金额:
    $ 30万
  • 项目类别:
    Fellowship Award
Postdoctoral Fellowship: MPS-Ascend: Coherent Control of Nonlinear Schrodinger Dynamics in the Presence of Uncertainty
博士后奖学金:MPS-Ascend:不确定性情况下非线性薛定谔动力学的相干控制
  • 批准号:
    2316622
  • 财政年份:
    2023
  • 资助金额:
    $ 30万
  • 项目类别:
    Fellowship Award
Postdoctoral Fellowship: MPS-Ascend: Jet-Energy Loss Measurements with the sPHENIX Detector
博士后奖学金:MPS-Ascend:使用 sPHENIX 探测器进行射流能量损失测量
  • 批准号:
    2316651
  • 财政年份:
    2023
  • 资助金额:
    $ 30万
  • 项目类别:
    Fellowship Award
Postdoctoral Fellowship: MPS-Ascend: The Ghost Algebra for Correlation Functions & Convexity of Anosov Representations
博士后奖学金:MPS-Ascend:相关函数的幽灵代数
  • 批准号:
    2316685
  • 财政年份:
    2023
  • 资助金额:
    $ 30万
  • 项目类别:
    Fellowship Award
{{ showInfoDetail.title }}

作者:{{ showInfoDetail.author }}

知道了