LEAPS-MPS: Synthesis of Photoactive Manganese Complexes With Carbene Ligands

LEAPS-MPS：用卡宾配体合成光活性锰配合物

• 批准号: 2316810
• 负责人: Daniela Arias-Rotondo
• 金额: $ 25万
• 依托单位: Kalamazoo College
• 依托单位国家: 美国
• 项目类别: Standard Grant
• 财政年份: 2023
• 资助国家: 美国
• 起止时间: 2023-09-01 至 2025-08-31
• 项目状态: 未结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=2316810&HistoricalAwards=false
• 关键词: LEAPS; MPS; Synthesis; Photoactive; Manganese

In this project managed by the Chemistry Division at NSF, Professor Daniela Arias-Rotondo and her students at Kalamazoo College will design, prepare, and study manganese-based compounds that could have potential applications in converting solar energy into electricity. Manganese is a low-cost, low-toxicity alternative to the materials currently used for these applications. Students of varied backgrounds will work on this project, closely mentored by Prof. Arias-Rotondo, who will also establish peer-mentoring opportunities for the project participants. Additionally, Prof. Arias-Rotondo will re-design the laboratory portion of the Inorganic Chemistry course offered at Kalamazoo College to give students a research-like experience in the class. To accomplish this goal, some of the compounds developed in this research project will be incorporated into the Inorganic Chemistry teaching lab.The photophysics of manganese coordination complexes is an underexplored research area, as is the organometallic chemistry of manganese in low oxidation states. Prof. Arias-Rotondo and her students aim to synthesize carbene ligands to coordinate to manganese in several oxidation states and characterize the resulting compounds through a combination of NMR and optical spectroscopy, x-ray diffraction, and electrochemistry. Computational modelling will be used to aid the interpretation of experimental data, creating a more thorough description of the molecular and electronic structure of these coordination complexes. The PI seeks to synthetically modified ligands to study the effect of substituents on the properties of the Mn compounds. This project could potentially yield robust photoactive manganese complexes with charge-separated excited states that can be accessed with visible light as well as design principles to prepare other Mn compounds and tailor their properties.This award reflects NSF's statutory mission and has been deemed worthy of support through evaluation using the Foundation's intellectual merit and broader impacts review criteria.

在这个由国家科学基金会化学部管理的项目中，卡拉马祖学院的Daniela Arias-Rotondo教授和她的学生将设计、准备和研究可能在将太阳能转化为电能方面具有潜在应用的锰基化合物。锰是目前用于这些应用的材料的一种低成本、低毒性的替代品。不同背景的学生将在Arias-Rotondo教授的密切指导下参与这个项目，他还将为项目参与者提供同行指导的机会。此外，阿里亚斯-罗通多教授将重新设计卡拉马祖学院提供的无机化学课程的实验室部分，让学生在课堂上获得类似研究的体验。为了实现这一目标，本研究项目中开发的一些化合物将纳入无机化学教学实验室。锰配合物的光物理是一个未被探索的研究领域，低氧化态下的锰的有机金属化学也是一个未被探索的领域。Arias-Rotondo教授和她的学生的目标是合成卡宾配体，以便在几种氧化态与锰配位，并通过核磁共振和光学光谱、X射线衍射和电化学相结合的方法对所得化合物进行表征。计算模型将被用来帮助解释实验数据，创建更全面的描述这些配位络合物的分子和电子结构。PI试图通过合成修饰配体来研究取代基对锰化合物性质的影响。该项目可能会产生强大的具有电荷分离激发态的光活性锰络合物，可以用可见光访问，以及用于制备其他锰化合物和调整其性能的设计原则。该奖项反映了NSF的法定使命，并通过使用基金会的智力优势和更广泛的影响审查标准进行评估，被认为值得支持。