SFB 1176: Molekulare Strukturierung weicher Materie
SFB 1176: Molekulare Strukturierung weicher Materie
批准号:
259079535
负责人:
金额:
$0.0万
依托单位国家:
德国
项目类别:
Collaborative Research Centres
财政年份:
2016
资助国家:
德国
项目状态:
已结题
起止时间:
2015-12-31 至 2019-12-31
中文摘要
1176合作研究中心旨在建立具有迄今为止无与伦比的三维结构控制程度的聚合材料合成。在这样做的过程中,目标分子精度使定量的结构-性质关系研究,定义的功能,或获得新型材料,最终导致广泛的新型应用。通过维度组织原则关注软材料的分子结构,有助于对合成挑战进行分类,并将科学发现从一个维度转移到另一个维度。高分子材料的性质主要取决于其分子结构及其空间排列和连接。这种分子结构可以是沿着链的小构建块的序列(一维),链长集合的均匀性或大分子内分支的程度。沿着链的功能的精确位置可以确定和调节链在溶液中的行为-所谓的卷曲行为。表面(二维)可以由重复单元组成,也可以用赋予表面特定功能的大分子修饰。在网络(三维)中,生成的材料的复杂特性由单个网格的长度或功能构建块的顺序决定。CRC 1176中的这些高精度大分子的合成是由表面分析平台,新颖的表征方法以及分子动力学和量子力学计算补充的。
英文摘要
The Collaborative Research Centre 1176 aims to establish the synthesis of polymeric materials with a so far unmatched degree of structural control in three dimensions. In doing so, the targeted molecular precision enables quantitative structure-property relationship investigations, a defined function, or access to a novel class of materials, eventually resulting in a wide range of novel applications The focus on the molecular structure of soft materials by a dimensional organising principle facilitates to classify the synthetic challenges as well as to transfer the scientific findings from one dimension to another. The properties of macromolecular materials are primarily determined by their molecular structure and its spatial arrangement and linkage. This molecular structure can be the sequence of small building blocks along the chain (one-dimensional), the uniformity of the chain-length ensemble or the degree of branching within the macromolecule. The precise placement of functionalities along the chain can determine and regulate the behaviour of the chain in solution - the so-called coiling behaviour. Surfaces (two-dimensional) can consist of repeating units or be decorated with macromolecules, which impart specific function to the surface. In a network (three-dimensional), the complex properties of the resulting material are determined by the length of the single mesh or by the sequence of the building blocks of functionalities. The synthesis of these high-precision macromolecules within CRC 1176 is complemented by a surface analysis platform, novel characterisation methods as well as molecular dynamic and quantum mechanical calculations.
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