Elucidate the quantum structure of high-spin systems through a multi- experiment approach coupled with consistent single-platform analysis and simulation

通过多实验方法结合一致的单平台分析和模拟来阐明高自旋系统的量子结构

• 批准号: 277567762
• 负责人: Dr. Joscha Nehrkorn
• 金额: --
• 依托单位: Department of Chemistry
• 依托单位国家: 德国
• 项目类别: Research Fellowships
• 财政年份: 2015
• 资助国家: 德国
• 起止时间: 2014-12-31 至 2015-12-31
• 项目状态: 已结题
• 来源: https://gepris.dfg.de/gepris/projekt/277567762?language=en
• 关键词: Elucidate; quantum; structure; spin; systems

In this fellowship two important issues in the spectroscopic investigation of spin interactions in high-spin magnetic molecules will be tackled:1. Investigation of the effect of higher-order Zeeman terms on high-field EPR spectra2. Discrimination of easy and hard axis magnetic anisotropy using polarization dependence of EPR spectra.

本研究将解决高自旋磁性分子自旋相互作用光谱研究中的两个重要问题：1。 高阶塞曼项对高场EPR谱影响的研究2。 利用EPR谱的极化相关性判别易轴和难轴磁各向异性。

项目成果

Analysis of Magnetic Anisotropy and the Role of Magnetic Dilution in Triggering Single-Molecule Magnet (SMM) Behavior in a Family of CoII YIII Dinuclear Complexes with Easy-Plane Anisotropy.

• DOI: 10.1002/chem.201702099
• 发表时间: 2017-08
• 期刊: Chemistry
• 作者: M. Palacios;J. Nehrkorn;E. Suturina;E. Ruiz;Silvia Gómez-Coca;K. Holldack;A. Schnegg;J. Krzystek-