Extension of conventional solid state methods: Microwave synthesis of transition metal carbides

传统固态方法的延伸：过渡金属碳化物的微波合成

• 批准号: 282251678
• 负责人: Professorin Dr. Christina Birkel
• 金额: --
• 依托单位: Fachgebiet Anorganische Chemie
• 依托单位国家: 德国
• 项目类别: Research Grants
• 财政年份: 2015
• 资助国家: 德国
• 起止时间: 2014-12-31 至 2018-12-31
• 项目状态: 已结题
• 来源: https://gepris.dfg.de/gepris/projekt/282251678?language=en
• 关键词: Extension; conventional; solid; state; methods

In the proposed project, we will explore microwave heating as a synthesis tool to access a variety of binary and more complex transition metal carbides. Solid state microwave reactions have been widely used to prepare a multitude of inorganic compounds that often even exhibit improved properties. Based on our experience with microwave reactions using a domestic microwave oven (e.g. half-Heusler intermetallic compounds and oxide phosphors), we will extend our efforts to an additional class of compounds, namely transition metal carbides. Here, a laboratory-grade microwave reactor is the central piece of equipment that will be used during the course of this project. Although promising results can already be achieved with a domestic microwave oven, only the research-grade microwave will allow us to take full advantage of the microwave heating technique. It offers a number of advantages in contrast to the domestic microwave oven, most importantly the possibility to monitor the temperature during the reaction as well as much higher safety standards. Both aspects are of major importance for the here proposed project because they will enable highly reproducible syntheses as well as safe reaction procedures in the laboratory.Due to the excellent coupling behavior of different forms of carbon with the microwave radiation leading to rapid heating rates, carbides are among the ideal candidates to exploit microwave heating for their synthesis. Binary transition metal carbides, such as Fe3C, Co2C, will be studied to evaluate the various possible synthesis methods, direct reaction from the elements and carbothermal reduction of the respective oxides. We will then move towards the hexagonal MAX phases that are more complex carbides with the general formula Mn+1AXn, where M is an early transition metal, A is an A-group element (mostly in groups 13 and 14) and X is either carbon or nitrogen. Many of these compounds are known and well studied. However, not that much work has been devoted to finding additional MAX phases with later transition metals, such as Mn, Fe and Co. We will therefore focus on possible solid solutions of known MAX compounds with later transition metals and are particularly interested in their magnetic properties. Besides, so called MXene compounds will be also be investigated. They are an exfoliated version of the MAX phases where the A layer has been etched away. Since some of these compounds exhibit semiconducting instead of metallic behavior, they are expected to show promising thermoelectric properties.

在拟议的项目中，我们将探索微波加热作为合成工具，以获得各种二元和更复杂的过渡金属碳化物。固态微波反应已被广泛用于制备许多无机化合物，这些化合物通常甚至表现出改进的性质。基于我们使用家用微波炉进行微波反应的经验（例如半赫斯勒金属间化合物和氧化物磷光体），我们将努力扩展到另一类化合物，即过渡金属碳化物。在这里，实验室级微波反应器是该项目过程中将使用的核心设备。虽然家用微波炉已经可以实现有希望的结果，但只有研究级微波才能让我们充分利用微波加热技术。与家用微波炉相比，它具有许多优点，最重要的是可以在反应过程中监控温度以及更高的安全标准。这两个方面对于这里提出的项目都是非常重要的，因为它们将使高度可重复的合成以及在实验室中的安全反应程序。由于不同形式的碳与微波辐射的良好耦合行为导致快速加热速率，碳化物是利用微波加热进行合成的理想候选者之一。二元过渡金属碳化物，如Fe3C，Co2C，将被研究，以评估各种可能的合成方法，从元素的直接反应和碳热还原各自的氧化物。然后我们将转向六方MAX相，其是具有通式Mn+1AXn的更复杂的碳化物，其中M是前过渡金属，A是A族元素（主要在第13族和第14族中），X是碳或氮。这些化合物中有许多是已知的，并得到了充分的研究。然而，没有那么多的工作一直致力于寻找额外的MAX相与后过渡金属，如锰，铁和钴，因此，我们将集中在已知的MAX化合物与后过渡金属的可能的固溶体，并特别感兴趣的是它们的磁性。此外，还将研究所谓的MXene化合物。它们是MAX相的剥落版本，其中A层已被蚀刻掉。由于这些化合物中的一些表现出半导体而不是金属行为，因此它们有望显示出有前途的热电性能。

项目成果

Adding a New Member to the MXene Family: Synthesis, Structure, and Electrocatalytic Activity for the Hydrogen Evolution Reaction of V4C3Tx

• DOI: 10.1021/acsaem.8b00652
• 发表时间: 2018-08-01
• 期刊: ACS APPLIED ENERGY MATERIALS
• 影响因子: 6.4
• 作者: Tran, Minh H.;Schaefer, Timo;Birkel, Christina S.
• 通讯作者: Birkel, Christina S.

Non-conventional synthesis and magnetic properties of MAX phases (Cr/Mn)2AlC and (Cr/Fe)2AlC

• DOI: 10.1039/c7tc00112f
• 发表时间: 2017-06-21
• 期刊: JOURNAL OF MATERIALS CHEMISTRY C
• 影响因子: 6.4
• 作者: Hamm, Christin M.;Bocarsly, Joshua D.;Birkel, Christina S.
• 通讯作者: Birkel, Christina S.

Structural, magnetic and electrical transport properties of non-conventionally prepared MAX phases V2AlC and (V/Mn)2AlC

• DOI: 10.1039/c7qm00488e
• 发表时间: 2017
• 期刊: Materials Chemistry Frontiers
• 影响因子: 7
• 作者: C. M. Hamm;M. Dürrschnabel;L. Molina‐Luna;R. Salikhov;D. Spoddig;M. Farle;U. Wiedwald;Christina S. Birkel

Non-conventional Synthesis of the 413 MAX Phase V4AlC3

• DOI: 10.1002/zaac.201600370
• 发表时间: 2016-12
• 期刊: Zeitschrift für anorganische und allgemeine Chemie
• 作者: C. M. Hamm;Tim Schäfer;Hongbin Zhang;Christina S. Birkel