非イオン性界面活性剤の六方相により得られたフォトニックヒドロゲルの構造と特性

非离子表面活性剂六方相光子水凝胶的结构与性能

• 批准号: 21F20769
• 负责人: グン 剣萍
• 金额: $ 1.47万
• 依托单位: Hokkaido University
• 依托单位国家: 日本
• 项目类别: Grant-in-Aid for JSPS Fellows
• 财政年份: 2021
• 资助国家: 日本
• 起止时间: 2021-04-28 至 2023-03-31
• 项目状态: 已结题
• 来源: https://kaken.nii.ac.jp/en/grant/KAKENHI-PROJECT-21F20769/
• 关键词: Photonic hydrogel; lamellar bilayers; self-assembly; mechanical properties; surfactant

In-situ structural analysis by USAXS have revealed that the deformation mechanisms within the hydrogels have been modified even by very small amounts of co-surfactants, meaning that the chemistry of the co-surfactant is of utmost importance in this system. Such observations have led us to hypothesize that interfacial interactions between the lamellae and the gel matrix between lamellae play an important role in the deformation mechanisms during uniaxial loading or cyclic loading by helping to dissipate more energy. We expect that such understanding will help to deepen our knowledge of this system in future studies involving the mechanical response under different loading conditions. The results of this research project have been summarized into an article, submitted to the journal ACS Omega (currently under review). Thus, this research project will be published online soon. Thanks to the novelty of the work, other fundamental questions are expected to be elucidated especially regarding the mechanical behavior of this type of hydrogel. Unfortunately, USAXS conditions were not suitable to obtain any data at solution state and the SAXS machine available at the university did not give good results (even with a custom-made sample-holder) due to a lack of beam power.

USAXS 的原位结构分析表明，即使极少量的辅助表面活性剂也可以改变水凝胶内的变形机制，这意味着辅助表面活性剂的化学性质在该系统中至关重要。这些观察结果使我们推测，片层和片层之间的凝胶基质之间的界面相互作用通过帮助耗散更多能量，在单轴加载或循环加载期间的变形机制中发挥重要作用。我们希望这种理解将有助于在未来涉及不同负载条件下的机械响应的研究中加深我们对该系统的了解。该研究项目的结果已总结成一篇文章，提交给《ACS Omega》杂志（目前正在审稿中）。因此，该研究项目将很快在线发表。由于这项工作的新颖性，其他基本问题有望得到阐明，特别是关于此类水凝胶的机械行为。不幸的是，USAXS 条件不适合在溶液状态下获取任何数据，并且由于缺乏光束功率，大学可用的 SAXS 机器没有给出良好的结果（即使使用定制的样品架）。

项目成果

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Mechanical reinforcement of self-assembled photonic hydrogels by small amounts of co-surfactants

少量辅助表面活性剂对自组装光子水凝胶的机械增强

• 发表时间: 2023
• 作者: X. Zhu;M. Bescond;B. Bastard;C. Salhani;N. Nagai;and K. Hirakawa;Milena Lama
• 通讯作者: Milena Lama

Modification of the macroscopic properties of lamellar photonic hydrogels by small amounts of co-surfactants

少量辅助表面活性剂改变层状光子水凝胶的宏观性能

• 发表时间: 2022
• 作者: Fabian Eisenstein;Milena Lama
• 通讯作者: Milena Lama

Modification of the mechanical response of self-assembled photonic hydrogels by small amounts of co-surfactants

通过少量辅助表面活性剂改变自组装光子水凝胶的机械响应

• 发表时间: 2022
• 作者: Eisenstein Fabian;Yanagisawa Haruaki;Kashihara Hiroka;Kikkawa Masahide;Tsukita Sachiko;Danev Radostin;Kerstin Fooken;Courtney Dunphy;Milena Lama
• 通讯作者: Milena Lama

Role of co-surfactants on improving the mechanical response of lamellar photonic hydrogels

助表面活性剂在改善层状光子水凝胶机械响应中的作用

• 发表时间: 2022
• 作者: Danev Radostin;Belousoff Matthew;Liang Yi-Lynn;Zhang Xin;Eisenstein Fabian;Wootten Denise;Sexton Patrick M.;Milena Lama
• 通讯作者: Milena Lama