カーバイド前駆体を用いた低温ナノポーラスグラフェン合成法の開発

利用碳化物前驱体开发低温纳米多孔石墨烯合成方法

• 批准号: 19K15389
• 负责人: 韓 久慧
• 金额: $ 2.75万
• 依托单位: Tohoku University
• 依托单位国家: 日本
• 项目类别: Grant-in-Aid for Early-Career Scientists
• 财政年份: 2019
• 资助国家: 日本
• 起止时间: 2019-04-01 至 2023-03-31
• 项目状态: 已结题
• 来源: https://kaken.nii.ac.jp/en/grant/KAKENHI-PROJECT-19K15389/
• 关键词: Nanoporous graphene; Nanoporous carbon; Carbide mediation; Chemical dealloying; Electrocatalyst; Electrode; Single-atom catalysts; Porous carbon; Sodium ion battery; Composite; Metallic carbides; Dealloying; Na-ion battery; ナノポーラスグラフェン; カーバイ

Through carbide mediation and chemical dealloying, new 3D nanoporous graphene, 3D nanoporous amorphous carbon, and 3D nanoporous graphene/carbon composite materials with precisely controlled structural features and desirable physicochemical properties have been developed. These new materials lead to the creation of advanced electrocatalysts and electrodes, such as mesoporous N-doped graphene for the oxygen reduction reaction, nanoporous graphene anchored Pt single-atom catalyst for electrochemical hydrogen production, mesoporous graphene/TiO2 composite for dense Li-ion battery anode, and nanoporous amorphous carbon for high-rate Na-ion battery anode. These 3D nanoporous graphene and carbon enable high-efficiency energy conversion and storage as a new class of functional materials.

通过碳化物调理和化学去合金化，制备了具有精确可控结构特征和良好物理化学性能的新型3D纳米孔石墨烯、3D纳米孔无定形碳和3D纳米孔石墨烯/碳复合材料。这些新材料催生了先进的电催化剂和电极，如用于氧还原反应的介孔N掺杂石墨烯，用于电化学制氢的纳米孔石墨烯锚定的铂单原子催化剂，用于高密度锂离子电池负极的介孔石墨烯/二氧化钛复合材料，以及用于高倍率钠离子电池负极的纳米孔无定形碳。这些3D纳米多孔石墨烯和碳作为一类新的功能材料实现了高效的能量转换和存储。

项目成果

Dealloyed nanoporous materials for electrochemical energy conversion and storage

• DOI: 10.1016/j.enchem.2022.100069
• 发表时间: 2022-01-01
• 期刊: ENERGYCHEM
• 影响因子: 25.1
• 作者: Sang, Qinqin;Hao, Shuo;Ding, Yi
• 通讯作者: Ding, Yi

Dynamic shrinkage of metal-oxygen bonds in atomic Co-doped nanoporous RuO2 for acidic oxygen evolution

• DOI: 10.1007/s40843-021-1912-8
• 发表时间: 2022-01
• 期刊: Science China Materials
• 作者: Qiuli Wu;Kang Jiang;Jiuhui Han;Dechao Chen;M. Luo;J. Lan;Ming Peng;Yongwen Tan

材料化学: 化学的脱合金化法を用いて新しい多孔質カーボン電極を合成

材料化学：使用化学脱合金方法合成新型多孔碳电极

Dilute molybdenum atoms embedded in hierarchical nanoporous copper accelerate the hydrogen evolution reaction

嵌入分级纳米孔铜中的稀钼原子加速析氢反应

• DOI: 10.1016/j.scriptamat.2020.09.011
• 发表时间: 2021
• 期刊: Scripta Materialia
• 影响因子: 6
• 作者: Wei Peng;Min Luo;Yang Zhao;Jiao Lan;Ming Peng;Jiuhui Han;Hongju Li;Yongwen Tan
• 通讯作者: Yongwen Tan

2D graphene in a 3D architecture: Nanoporous graphene materials for emerging batteries

3D 架构中的 2D 石墨烯：用于新兴电池的纳米多孔石墨烯材料

• 发表时间: 2020
• 作者: 森廣 邦彦;石鍋 拓郎;高津 正子;大澤 毅;岡本 晃充;Jiuhui Han
• 通讯作者: Jiuhui Han