Fundamental Studies on Lithium -Ion Batteries with High Specific Energy Density

高比能量密度锂离子电池基础研究

• 批准号: 392444663
• 负责人: Dr. Jie Li
• 金额: --
• 依托单位: Department of Chemistry
• 依托单位国家: 德国
• 项目类别: Research Grants
• 财政年份: 2018
• 资助国家: 德国
• 起止时间: 2017-12-31 至 2020-12-31
• 项目状态: 已结题
• 来源: https://gepris.dfg.de/gepris/projekt/392444663?language=en
• 关键词: Fundamental; Studies; Lithium; Ion; Batteries

This project will combine the experiments and theory methods to study the new generation of high-capacity positive electrode materials Li2(M1/M2)O3 (M1, M2 = Mn, Ru, Ni, Co, etc.) and compatible electrolytes for Li-ion batteries, construct and develop novel Li-ion battery system with high specific energy density. We will do controllable synthesis of the target materials with nano-composite structure via designing and optimizing materials synthesis methods, and explore the compatible high-voltage electrolyte systems. The electrochemical performance of the materials and corresponding electrolytes will be investigated systematically with different techniques. The electrochemical reaction mechanisms and the relationship between material structure and performance will also be characterized by different advanced techniques (such as in situ synchrotron radiation-based XRD, hard & soft X-ray absorption techniques, solid state NMR and on line mass spectroscopy) combining with first-principles calculations. We expected to get information and more understanding of crystal and local structural evolution, ionic valence changes and cation/anion ordering, oxygen evolution and interfacial properties etc. It is believed that such information and data will deepen our understanding of equilibrium relationship between O2- and O(2-m)-, utilization scale of new anionic redox process. These results will impact the future R&D of new generation of positive electrode materials and the compatible high-voltage electrolyte systems, finally the Li-ion batteries with high-energy density.

本项目将联合收割机的实验和理论方法相结合，研究新一代高容量正极材料Li 2（M1/M2）O 3（M1，M2 = Mn，Ru，Ni，Co等）。和锂离子电池相容性电解质，构建和开发新型高比能量密度锂离子电池体系。我们将通过设计和优化材料合成方法，实现具有纳米复合结构的目标材料的可控合成，并探索相容的高压电解质体系。将采用不同的技术系统地研究材料和相应电解质的电化学性能。电化学反应机理和材料结构与性能之间的关系也将通过不同的先进技术（如基于同步辐射的原位XRD，硬和软X射线吸收技术，固态NMR和在线质谱）结合第一性原理计算来表征。我们期望获得晶体和局部结构演化、离子价态变化和阳/阴离子有序、氧析出和界面性质等方面的信息和更多的了解，相信这些信息和数据将加深我们对O2-和O（2-m）-平衡关系、新的阴离子氧化还原过程的利用规模的理解。这些结果将影响未来新一代正极材料和兼容的高压电解质体系的研发，最终影响高能量密度的锂离子电池。

项目成果

Preferential occupation of Na in P3-type layered cathode material for sodium ion batteries

• DOI: 10.1016/j.nanoen.2020.104535
• 发表时间: 2020-04
• 期刊: Nano Energy
• 影响因子: 17.6
• 作者: Li Zhang;Jun Wang;Jinke Li;G. Schuck;M. Winter;G. Schumacher;Jie Li

Understanding the effect of Nb substitution on Li-Mn-rich layered oxides

• DOI: 10.1016/j.electacta.2021.138801
• 发表时间: 2021-07-04
• 期刊: ELECTROCHIMICA ACTA
• 影响因子: 6.6
• 作者: Brinkmann, Jan-Paul;Rodehorst, Uta;Li, Jie
• 通讯作者: Li, Jie

Tin modification of sodium manganese hexacyanoferrate as a superior cathode material for sodium ion batteries

• DOI: 10.1016/j.electacta.2020.135928
• 发表时间: 2020-05-10
• 期刊: ELECTROCHIMICA ACTA
• 影响因子: 6.6
• 作者: Li, Jinke;He, Xin;Li, Jie
• 通讯作者: Li, Jie

Stabilizing P3‐Type Oxides as Cathodes for High‐Rate and Long‐Life Sodium Ion Batteries by Disordered Distribution of Transition Metals

• DOI: 10.1002/smtd.202000422
• 发表时间: 2020-10
• 作者: Li Zhang;Jun Wang;G. Schuck;Fanxing Xi;Leilei Du;M. Winter;G. Schumacher;Jie Li

Tailoring of gradient particles of Li rich layered cathodes with mitigated voltage decay for lithium ion batteries.

• DOI: 10.1021/acsami.0c10410
• 发表时间: 2020-08
• 期刊: ACS applied materials & interfaces
• 影响因子: 9.5
• 作者: Xiaokang Ju;X. Hou;Thomas Beuse;Zhongqing Liu;Leilei Du;Jan‐Paul Brinkmann;Elie Paillard;Taihong Wang