Creation and structure analysis of hierarchical metal-complex-assembled space based on lipid bilyers

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The research project targeted creating novel "highly-functional chemical reaction field" in which electron transfer, mass transfer and chemical reaction linked. We tried to establish basic technique for creation and structural analysis of "hierarchical metal-complex-assembled space" in which various functional metal complexes were incorporated rationally. In the project, we succeeded in the following points, (1) synthesis of lipophilic ligands and lipophilic metal complexes, (2) incorporation of metal complexes in the inner aqueous space of liposome, (3) incorporation of metal complexes on the liposome surface and (4) structure evaluation of liposome-metal complex composites.