Solubilization of weakly polar compounds in micellar systems (A09*)

胶束溶剂体系中的化学反应如氢化、氢化酯化或氢化胺化导致弱极性产物（醛、甲酯和胺）。这些弱极性化合物可以溶解在胶束中。项目A9 N将开发一个全新的模型，该模型将胶束形成的详细模型与PC-SAFT相结合，以解释系统的非理想性。这一新模型将通过实验得到验证。新模型将允许计算弱极性组分在周围水相和胶束之间的分配系数。

Chemical reactions such as hydroformylation, hydroesterfication, or hydroamination) in micellar sol-vent systems lead to weakly-polar products (aldehydes, methyl esters, and amines). These weakly-polar compounds can be solubilized in the micelles. The project A9 N will develop a completely new model, which combines a detailed model for micelle formation with PC-SAFT accounting for the non-ideality of the system. This new model will be verified via experiments. The new model will allow cal-culating the distribution coefficients of the weakly-polar components between a surrounding water phase and the micelles.