Electro- and Photocatalytic CO2 Reduction with [FeNi]-Chalcogenides
使用 [FeNi]-硫属化物电催化和光催化 CO2 还原
基本信息
- 批准号:397789315
- 负责人:
- 金额:--
- 依托单位:
- 依托单位国家:德国
- 项目类别:Research Grants
- 财政年份:2018
- 资助国家:德国
- 起止时间:2017-12-31 至 2022-12-31
- 项目状态:已结题
- 来源:
- 关键词:
项目摘要
Carbon dioxide is a major greenhouse gas and assumed to be one of the key factors responsible for the current climate change. Despite its low reactivity, utilization of CO2 is of utmost interest for society and will contribute to lowering the increase of its total concentration in air. Besides its conversion into organic carbonates, the thermodynamic uphill conversion, reduction of CO2 to afford industrial important chemicals and fuels is a promising pathway towards the recycling of CO2 in an artificial carbon cycle. Especially, photo- and electrocatalytic reduction processes will be essential for such conversions into various products. Contrary to industrial catalysis, nature possesses highly sophisticated machineries to allow for a selective reduction of CO2 under mild conditions. Although such enzymatic active sites are well-known and comprise a [NiFe] heterobimetallic reaction center, this motif was not yet investigated for heterogeneous catalytic reduction of CO2. We herein aim at the characterization and advancement of [FeNi]- chalcogenides as heterogeneous photo- and electrocatalysts for the reduction of CO2 in a proof-of-principle study.
二氧化碳是一种主要的温室气体,被认为是造成当前气候变化的关键因素之一。尽管其反应性低,但CO2的利用对社会来说是最重要的,并将有助于降低其在空气中总浓度的增加。除了将其转化为有机碳酸盐外,热力学上坡转化,CO2的还原以提供工业上重要的化学品和燃料是CO2在人工碳循环中再循环的有前途的途径。特别是,光催化还原和电催化还原过程对于这种转化为各种产品至关重要。与工业催化相反,大自然拥有高度复杂的机制,可以在温和的条件下选择性地还原二氧化碳。虽然这样的酶活性位点是众所周知的,并包括一个[NiFe] heteroalkylation反应中心,这个主题还没有研究CO2的多相催化还原。我们在此的目的是表征和进步的[FeNi]-硫族化合物作为异构光和电催化剂的原理验证研究中的CO2还原。
项目成果
期刊论文数量(0)
专著数量(0)
科研奖励数量(0)
会议论文数量(0)
专利数量(0)
数据更新时间:{{ journalArticles.updateTime }}
{{
item.title }}
{{ item.translation_title }}
- DOI:
{{ item.doi }} - 发表时间:
{{ item.publish_year }} - 期刊:
- 影响因子:{{ item.factor }}
- 作者:
{{ item.authors }} - 通讯作者:
{{ item.author }}
数据更新时间:{{ journalArticles.updateTime }}
{{ item.title }}
- 作者:
{{ item.author }}
数据更新时间:{{ monograph.updateTime }}
{{ item.title }}
- 作者:
{{ item.author }}
数据更新时间:{{ sciAawards.updateTime }}
{{ item.title }}
- 作者:
{{ item.author }}
数据更新时间:{{ conferencePapers.updateTime }}
{{ item.title }}
- 作者:
{{ item.author }}
数据更新时间:{{ patent.updateTime }}
Professor Dr. Ulf-Peter Apfel其他文献
Professor Dr. Ulf-Peter Apfel的其他文献
{{
item.title }}
{{ item.translation_title }}
- DOI:
{{ item.doi }} - 发表时间:
{{ item.publish_year }} - 期刊:
- 影响因子:{{ item.factor }}
- 作者:
{{ item.authors }} - 通讯作者:
{{ item.author }}
{{ truncateString('Professor Dr. Ulf-Peter Apfel', 18)}}的其他基金
Bio-inspired Carbon Dioxide Activation on Heterobimetallic Complexes
异双金属配合物的仿生二氧化碳活化
- 批准号:
256826550 - 财政年份:2014
- 资助金额:
-- - 项目类别:
Independent Junior Research Groups
Enzyme, Electrode and Reactor Design for Enzymatic Cascade Reactions
酶级联反应的酶、电极和反应器设计
- 批准号:
536424308 - 财政年份:
- 资助金额:
-- - 项目类别:
Priority Programmes
Metal cooperativity for visible-light driven CO2 reduction with new photosensitizers and catalysts (CO2-COP)
新型光敏剂和催化剂对可见光驱动二氧化碳还原的金属协同作用(CO2-COP)
- 批准号:
428643898 - 财政年份:
- 资助金额:
-- - 项目类别:
Research Grants
Electrobiochemistry and whole-cell biocatalysis: Power to value-added products through separated anode/cathode reactions
电化学和全细胞生物催化:通过分离的阳极/阴极反应为增值产品提供动力
- 批准号:
536337083 - 财政年份:
- 资助金额:
-- - 项目类别:
Priority Programmes
Establishing a sustainable methanogenic carbon dioxide reduction in bioelectrochemical systems and identification of kinetic and thermodynamic constraints.
在生物电化学系统中建立可持续的产甲烷二氧化碳还原并确定动力学和热力学约束。
- 批准号:
445401355 - 财政年份:
- 资助金额:
-- - 项目类别:
Research Grants
Cyclam Based Transition Metal Complexes and Their Performance in Established and New Application Areas
基于 Cyclam 的过渡金属配合物及其在现有和新应用领域中的性能
- 批准号:
383043091 - 财政年份:
- 资助金额:
-- - 项目类别:
Research Grants
Novel bio-synthetic constructs for the analysis and manipulation of the hydrogen catalysis of [FeFe]-hydrogenases
用于分析和操作[FeFe]-氢化酶氢催化的新型生物合成结构
- 批准号:
436793189 - 财政年份:
- 资助金额:
-- - 项目类别:
Research Grants
Design of an electrochemical bioproduction system for piperazines
哌嗪电化学生物生产系统的设计
- 批准号:
445397982 - 财政年份:
- 资助金额:
-- - 项目类别:
Priority Programmes
相似海外基金
CAREER: Photocatalytic Transfer Hydrogenation of CO2 Using Transition Metal Cluster Arrays
职业:使用过渡金属簇阵列进行二氧化碳光催化转移氢化
- 批准号:
2237345 - 财政年份:2023
- 资助金额:
-- - 项目类别:
Continuing Grant
Proposal of design guidelines for improving CO2 reduction selectivity in photocatalytic CO2 reduction with water as an electron source
提高以水为电子源的光催化 CO2 还原中 CO2 还原选择性的设计指南提案
- 批准号:
23K13779 - 财政年份:2023
- 资助金额:
-- - 项目类别:
Grant-in-Aid for Early-Career Scientists
Tandem Photocatalytic Conversion of CO2 to High Value Hydrocarbon Products
二氧化碳串联光催化转化为高价值碳氢化合物产品
- 批准号:
DP230101861 - 财政年份:2023
- 资助金额:
-- - 项目类别:
Discovery Projects
Collaborative Research: CAS-Climate: Structure, Dynamics, and Reaction Mechanism of Supported Single Atom for Photocatalytic CO2 Reduction
合作研究:CAS-气候:光催化CO2还原的负载单原子的结构、动力学和反应机制
- 批准号:
2321203 - 财政年份:2023
- 资助金额:
-- - 项目类别:
Standard Grant
Collaborative Research: CAS-Climate: Structure, Dynamics, and Reaction Mechanism of Supported Single Atom for Photocatalytic CO2 Reduction
合作研究:CAS-气候:光催化CO2还原的负载单原子的结构、动力学和反应机制
- 批准号:
2154837 - 财政年份:2022
- 资助金额:
-- - 项目类别:
Standard Grant
Collaborative Research: CAS-Climate: Structure, Dynamics, and Reaction Mechanism of Supported Single Atom for Photocatalytic CO2 Reduction
合作研究:CAS-气候:光催化CO2还原的负载单原子的结构、动力学和反应机制
- 批准号:
2154836 - 财政年份:2022
- 资助金额:
-- - 项目类别:
Standard Grant
Research and Development of Advanced Piezocatalytic and Piezo-photocatalytic CO2 Conversions into Valuable Fuels
先进压电催化和压电光催化二氧化碳转化为有价值燃料的研究与开发
- 批准号:
569053-2022 - 财政年份:2022
- 资助金额:
-- - 项目类别:
Alexander Graham Bell Canada Graduate Scholarships - Doctoral
Data-driven design of metal-organic frameworks for CO2 capture and photocatalytic conversion
用于二氧化碳捕获和光催化转化的金属有机框架的数据驱动设计
- 批准号:
2773471 - 财政年份:2022
- 资助金额:
-- - 项目类别:
Studentship
Efficient photocatalytic CO2 reduction using reversible complexation of the first-raw transition metal complexes
利用第一批过渡金属配合物原料的可逆络合作用高效光催化二氧化碳还原
- 批准号:
21K05082 - 财政年份:2021
- 资助金额:
-- - 项目类别:
Grant-in-Aid for Scientific Research (C)
Development of metal complexes as catalysts having Lewis acids in the second coordination sphere and application of those to photocatalytic CO2 reduction
第二配位层具有路易斯酸的金属配合物催化剂的开发及其在光催化CO2还原中的应用
- 批准号:
21K18973 - 财政年份:2021
- 资助金额:
-- - 项目类别:
Grant-in-Aid for Challenging Research (Exploratory)