Homogeneously catalyzed reductive amination of long-chain aldehydes and hydroaminomethylation of long-chain alkenes with integrated catalyst separation in thermos-regulated solvent systems (A11*)

在恒温溶剂系统中通过集成催化剂分离实现长链醛的均相催化还原胺化和长链烯烃的氢氨甲基化 (A11*)

• 批准号: 397796442
• 金额: --
• 依托单位: Lehrstuhl für Technische Chemie (TC)
• 依托单位国家: 德国
• 项目类别: CRC/Transregios
• 财政年份: 2018
• 资助国家: 德国
• 起止时间: 2017-12-31 至 2020-12-31
• 项目状态: 已结题
• 来源: https://gepris.dfg.de/gepris/projekt/397796442?language=en
• 关键词: Homogeneously; catalyzed; reductive; amination; long

In A11 N, the insights for the use of thermomorphic solvent systems (TMS) regarding reaction man-agement and catalyst recycling developed in A1 E are gradually transferred to new homogeneously catalyzed reactions. In case of the chosen exemplary reactions, reductive amination and hydroam-inomethylation, fundamental investigations on the catalytic system are required: optimal reaction conditions are to be found, with the selection of the solvent system being of greatest importance. Thus, both are therefore considered in an integrated manner. Finally, based on that, the choice is made for a one- or two-stage process management approach.

在A11 N中，在A1 E中发展的关于反应管理和催化剂回收的热形态溶剂系统(TMS)的使用的见解逐渐转移到新的均相催化反应上。对于所选择的典型反应，还原胺化和氢胺甲基化，需要对催化体系进行基础研究：找到最佳反应条件，其中溶剂体系的选择是最重要的。因此，两者都是以综合方式考虑的。最后，在此基础上，选择一个或两个阶段的过程管理方法。