Development and testing of integrated reaction and catalyst separation for the homogeneously cata-lyzed reductive amination and hydraminomethylation of long-chain alkenes in a miniplant (D03*)

小型工厂中长链烯烃均相催化还原胺化和氢氨甲基化的集成反应和催化剂分离的开发和测试 (D03*)

• 批准号: 398065193
• 金额: --
• 依托单位: Institut für Systemverfahrenstechnik V-4
• 依托单位国家: 德国
• 项目类别: CRC/Transregios
• 财政年份: 2018
• 资助国家: 德国
• 起止时间: 2017-12-31 至 2020-12-31
• 项目状态: 已结题
• 来源: https://gepris.dfg.de/gepris/projekt/398065193?language=en
• 关键词: Development; testing; integrated; reaction; catalyst

Making use of TMS and ONF for integrated catalyst recycling D3 N will realize the homogeneously catalyzed reductive amination (RA) and hydroaminomethylation (HAM) of long chain aldehydes and alkenes, respectively, in a continuously operated miniplant. Membrane-based separation concepts will also be developed and tested for the exclusion of water formed during the reaction. Long-term exper-imental investigations will be performed providing models suitable for process optimization in B9 N and D1 N. A non-invasive online measurement by in-situ IR spectroscopy will be developed to im-prove process insight and foster process control (D4 N).

利用TMS和ONF集成催化剂回收D3 N，将在连续运行的小型装置中分别实现长链醛和烯烃的均相催化还原胺化（RA）和氢氨甲基化（HAM）。还将开发和测试基于膜的分离概念，以排除反应过程中形成的水​​。将进行长期实验研究，提供适合 B9 N 和 D1 N 过程优化的模型。将开发通过原位红外光谱进行的非侵入式在线测量，以提高过程洞察力并促进过程控制（D4 N）。