Deep Eutectic Solvents: Solvent, water, and first steps of reactions involving biomass

低共熔溶剂：溶剂、水和涉及生物质的反应的第一步

• 批准号: 406232243
• 负责人: Professorin Dr. Barbara Kirchner
• 金额: --
• 依托单位: Mulliken Center for Theoretical Chemistry
• 依托单位国家: 德国
• 项目类别: Research Grants
• 财政年份: 2018
• 资助国家: 德国
• 起止时间: 2017-12-31 至 2023-12-31
• 项目状态: 已结题
• 来源: https://gepris.dfg.de/gepris/projekt/406232243?language=en
• 关键词: Deep; Eutectic; Solvents; Solvent; water

Gaining a fundamental understanding about how deep eutectic solvents (DES) media work is key to improve and tailor their properties, but this knowledge is severely lacking. This project aims to improve the present level of understanding. The three milestones of this project will be, understanding 1.) the building principles of DES, 2.) the interplay between DES and water and 3.) catalyzed organic reactions involving biomass products, mainly the conversion of pentoses and hexoses to furanic derivatives, which show excellent yield in DES. This shall be tackled by modeling specific examples of DESs, their water mixtures as well as systems including specific points along the reaction surface. These examples (with normal and inverse set up) are specifically chosen to allow gaining insight into the working principles of DESs.

深入了解共晶溶剂（DES）介质的工作原理是改进和调整其性能的关键，但这方面的知识严重缺乏。这个项目旨在提高目前的理解水平。这个项目的三个里程碑将是，理解1.)DES的构建原理，2.)DES与水的相互作用，3.)涉及生物质产品的催化有机反应，主要是戊糖和己糖转化为呋喃衍生物，这在DES中表现出优异的产率。这将通过模拟特定的DES例子，它们的水混合物以及包括反应表面特定点的系统来解决。这些示例（正常设置和反向设置）是专门选择的，以便深入了解DESs的工作原理。