Strategies for Molecular Repair and Self-regulation in Light-driven Catalysis for Hydrogen Evolution (A01)

光驱动催化析氢的分子修复和自我调节策略（A01）

• 批准号: 407394439
• 金额: --
• 依托单位: Institut für Anorganische Chemie I
• 依托单位国家: 德国
• 项目类别: CRC/Transregios
• 资助国家: 德国
• 项目状态: 未结题
• 来源: https://gepris.dfg.de/gepris/projekt/407394439?language=en
• 关键词: Strategies; Molecular; Repair; Self; regulation

A01 is dedicated to mechanistic studies on molecular dyads and triads for light-driven catalysis. The project will investigate how concepts for active repair of molecular dyads can be controlled by molecular design and how matrix integration can be utilized to prevent major degradation paths. Novel non-noble metal PS-CAT dyads will be explored, and the transfer of concepts for degradation prevention and molecular repair, from noble-metal model systems to non-noble metal dyads and triads will be studied.

A01致力于光驱动催化分子二联体和三联体的机理研究。该项目将研究如何通过分子设计来控制分子二元体主动修复的概念，以及如何利用基质整合来防止主要的降解路径。将探索新型非贵金属 PS-CAT 二元组，并研究从贵金属模型系统到非贵金属二元组和三元组的预防降解和分子修复概念的转移。