Biogeochemical interface formation in soils as controlled by different components

土壤中生物地球化学界面的形成受不同成分的控制

• 批准号: 40976401
• 负责人: Professorin Dr. Ingrid Kögel-Knabner
• 金额: --
• 依托单位: Lehrstuhl für Bodenkunde
• 依托单位国家: 德国
• 项目类别: Priority Programmes
• 财政年份: 2007
• 资助国家: 德国
• 起止时间: 2006-12-31 至 2016-12-31
• 项目状态: 已结题
• 来源: https://gepris.dfg.de/gepris/projekt/40976401?language=en
• 关键词: Biogeochemical; interface; formation; soils; controlled

We consider clay minerals, iron oxides and charcoal as major components controlling the formation of interfaces relevant for sorption of organic chemicals, as they control the assemblage of organic matter and mineral particles. We studied the formation of interfaces in batch incubation experiments with inoculated artificial soils consisting of model compounds (clay minerals, iron oxide, char) and natural soil samples. Results show a relevant contribution of both iron oxides and clay minerals to the formation of organic matter as sorptive interfaces for hydrophobic compounds. Thus, we intend to focus our work in the second phase on the characterization of the interface as formed by organic matter associated with clay minerals and iron oxides. The interfaces will be characterized by the BET-N2 and ethylene glycol monoethyl ether (EGME) methods and 129Xe and 13C NMR spectroscopy for determination of specific surface area, sorptive domains in the organic matter and microporosity. A major step forward is expected by the analysis of the composition of the interface at different resolution by reflected-light microscopy (mm scale), SEM (scanning electron microscopy, micrometer scale) and secondary ion mass spectrometry at the nanometer scale (nanoSIMS). The outcomes obtained in combination with findings from cooperation partners will help to unravel the contribution of different types of soil components on the formation and characteristics of the biogeochemical interfaces and their effect on organic chemical sorption.

我们认为粘土矿物，铁氧化物和木炭的主要成分控制相关的有机化学品的吸附界面的形成，因为它们控制的有机物和矿物颗粒的组合。我们研究了在批培养实验与接种人工土壤模型化合物（粘土矿物，氧化铁，炭）和天然土壤样品的界面的形成。结果表明，铁氧化物和粘土矿物形成的有机物作为疏水化合物的吸附界面的相关贡献。因此，我们打算把我们的工作集中在第二阶段的界面上的表征所形成的有机物与粘土矿物和铁氧化物。界面将通过BET-N2和乙二醇单乙醚（EGME）方法以及129 NMR和13 C NMR光谱法进行表征，以确定比表面积、有机物中的吸附域和微孔性。一个重大的进步是通过反射光显微镜（毫米级），扫描电子显微镜（扫描电子显微镜，微米级）和二次离子质谱在纳米级（nanoSIMS）在不同的分辨率的界面的组成分析。结合合作伙伴的研究结果，将有助于揭示不同类型的土壤成分对土壤地球化学界面的形成和特征的贡献及其对有机化学吸附的影响。