Electronic dynamics of luminescent 3MET systems (C09*)

发光 3MET 系统的电子动力学 (C09*)

• 批准号: 414357207
• 金额: --
• 依托单位: Institut für Physik
• 依托单位国家: 德国
• 项目类别: CRC/Transregios
• 财政年份: 2019
• 资助国家: 德国
• 起止时间: 2018-12-31 至 2021-12-31
• 项目状态: 已结题
• 来源: https://gepris.dfg.de/gepris/projekt/414357207?language=en
• 关键词: Electronic; dynamics; luminescent; 3MET; systems

This 3MET project studies 3MET complexes for their interaction with surfaces of various reactivity. It utilizes Mo2 complexes, multidecker lanthanide phthalocyanines, multi-metallic porphyrin complexes, and endohedral fullerenes. It exerts external control of the intramolecular cooperativity of 3MET complexes on surfaces by temperature or light in order to manipulate the electronic properties of substrate surfaces ranging from noble metals towards topological insulators and 2D graphene-like honey comb structures. Both approaches will significantly contribute to an in-depth understanding of intramolecular cooperativity effects for 3MET molecules on surfaces.

该 3MET 项目研究 3MET 复合物与各种反应性表面的相互作用。它利用Mo2配合物、多层镧系元素酞菁、多金属卟啉配合物和内嵌富勒烯。它通过温度或光对表面上的 3MET 配合物的分子内协同作用进行外部控制，以操纵从贵金属到拓扑绝缘体和 2D 类石墨烯蜂窝结构的基底表面的电子特性。这两种方法都将极大地有助于深入了解 3MET 分子在表面上的分子内协同效应。