Photocatalyst Luminescence Quenching as a Tool for Investigating Hydrogen Bonding and Lewis Acid-Induced C-F Bond Activation (A02)
Photocatalyst Luminescence Quenching as a Tool for Investigating Hydrogen Bonding and Lewis Acid-Induced C-F Bond Activation (A02)
光催化剂发光猝灭作为研究氢键和路易斯酸诱导的 C-F 键活化的工具 (A02)
批准号：
414778712
负责人：
金额：
$0.0万
依托单位国家：
德国
项目类别：
Collaborative Research Centres
财政年份：
2019
资助国家：
德国
项目状态：
已结题
起止时间：
2018-12-31 至 2021-12-31
中文摘要
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英文摘要
In this project, the influence of Fluorine-Specific hydrogen-bonding or Lewis acid interactions on photoredox-induced C-F bond activation is investigated. The strength of these Fluorine-Specific Interactions will be evaluated and quantified by measuring the quenching of photocatalysts in the presence of various H-bond donors and Lewis acids via luminescence spectroscopy. The data obtained will be then used to assist the development of new synthetically-useful defluorinative transformations of organofluorine compounds.
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