Indigoswitches to Quantify Fluorine‐Specific Interactions (C01)

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In this project indigo derivatives with (partially) fluorinated residues will be synthesized and the equilibrium (ratio of E and Z isomers) as well as the thermal half-life of the photogenerated meta-stable Z isomer will be measured under various conditions (solvent, temperature). In collaboration with groups from theory and spectroscopy, comprehensive insight into the energetics and dynam-ics of Fluorine-Specific Interactions will be gained and indigo derivatives will be optimized with regard to their switching behaviour.