Indigoswitches to Quantify Fluorine‐Specific Interactions (C01)

用于量化氟特定相互作用的靛蓝开关 (C01)

• 批准号: 414786002
• 金额: --
• 依托单位: Arbeitsgruppe Organische Chemie und funktionale Materialien
• 依托单位国家: 德国
• 项目类别: Collaborative Research Centres
• 财政年份: 2019
• 资助国家: 德国
• 起止时间: 2018-12-31 至 2021-12-31
• 项目状态: 已结题
• 来源: https://gepris.dfg.de/gepris/projekt/414786002?language=en
• 关键词: Indigoswitches; Quantify; Fluorine; Specific; Interactions

In this project indigo derivatives with (partially) fluorinated residues will be synthesized and the equilibrium (ratio of E and Z isomers) as well as the thermal half-life of the photogenerated meta-stable Z isomer will be measured under various conditions (solvent, temperature). In collaboration with groups from theory and spectroscopy, comprehensive insight into the energetics and dynam-ics of Fluorine-Specific Interactions will be gained and indigo derivatives will be optimized with regard to their switching behaviour.

在该项目中，将合成具有（部分）氟化残基的靛蓝衍生物，并将在各种条件（溶剂、温度）下测量平衡（E和Z异构体的比例）以及光生亚稳Z异构体的热半衰期。与理论和光谱学小组合作，将获得对氟特异性相互作用的能量学和动力学的全面了解，并将优化靛蓝衍生物的开关行为。