Molecular Recognition in Chiral Ionic Liquids as Basis for the Design and Synthesis of New Enantioselective Heterogeneous Catalysts and Membranes

手性离子液体中的分子识别作为新型对映选择性多相催化剂和膜设计和合成的基础

• 批准号: DP0664915
• 负责人: Prof Dr Thomas Maschmeyer
• 金额: $ 26.28万
• 依托单位: The University of Sydney
• 依托单位国家: 澳大利亚
• 项目类别: Discovery Projects
• 财政年份: 2006
• 资助国家: 澳大利亚
• 起止时间: 2006-01-19 至 2009-01-18
• 项目状态: 已结题
• 来源: https://dataportal.arc.gov.au/RGS/Web/Grants/DP0664915
• 关键词: Molecular; Recognition; Chiral; Ionic; Liquids

Molecules that can exist as mirror images, each with different, e.g., beneficial vs. toxic properties, underpin the pharmaceutical industry and increasingly new highly selective pesticides, and flavours/fragrances. Current commercial pathways often make mixtures of the mirror images that then need to be separated laboriously. These routes are inefficient, creating waste and use resources poorly. We aim to create solutions for these problems, using supported thin films of special, new types of salts that are liquid at room temperature, and which have other unusual chemical properties that make them ideally suited to enable efficient conversions.

可以作为镜像存在的分子，每个具有不同的，例如，有益与有毒的特性，支撑制药工业和越来越多的新的高选择性农药，香料/香料。 目前的商业途径通常会产生镜像的混合物，然后需要费力地将其分离。这些路线效率低下，造成浪费，资源利用率低。 我们的目标是为这些问题创造解决方案，使用特殊的新型盐的支撑薄膜，这些盐在室温下是液体，并且具有其他不寻常的化学性质，使它们非常适合实现高效转化。