Molecular Design and Preparation of Ferromagnetic Organic Materials

在本研究中，我们进行了实验和理论研究的标题项目。在实验方法上，采用热解法、热化学气相沉积法和有机合成法制备了各种有机磁性材料。磁化强度和ESR测量显示，它们具有相关的电子自旋排列，可能形成部分铁磁有序。在理论方法上，我们发展了非限制性Hartree-Fock晶体轨道方法，并将其应用于有机铁磁聚合物的设计。

In the present research, we have performed both experimental and theoretical studies on the titled Project. In the experimental approach, various organic magnetic materials have been prepared by the pyrolytic method, the thermal CVD method, and the organic synthetic method. The magnetization and the ESR measurements of these have revealed that they have correlated alignment of electron spins, possibly forming a partial ferromagnetic order. In the theoretical approach, we have developed the unrestricted Hartree-Fock crystal orbital method, and have applied this to the design of organic ferromagnetic polymers.