Research and Development of Novel Conducting Materials Consisting of Carbon Skeletons Based on a Molecular Engineering Approach

本项目总结如下：自旋特异性振动耦合的理论分析及与库珀对的关联讨论[j]。各种导电聚合物（包括新型聚合物）的电子结构计算。轻掺杂聚乙炔中链间传导机理的理论分析。聚噻吩和聚（3-甲基噻吩）的实验和理论分析。苯酚-甲醛树脂热解制备的原始和掺杂多聚材料的电输运特性实验分析。

Summary of this project is as follows.1. Theoretical analysis of spin-specific vibronic coupling and discussion in association with Cooper Pair.2. Calculations of the electronic structures of miscellaneous conductive polymers including novel polymers.3. Theoretical analysis of interchain conduction mechanism in lightly-doped polyacetylene.4. Experimental and theoretical analyses of polythiophene and poly(3-methylthiophene).5. Experimental analyses of electric transport properties of the pristine and the doped polyacenic materials prepared by pyrolytic treatment of phenol-formaldehyde resin.