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Syntheses of Metal Complexes of New Ligands Having Chiral Phosphorus

Syntheses of Metal Complexes of New Ligands Having Chiral Phosphorus
新型手性磷配体金属配合物的合成
批准号:
06453048
负责人:
KASHIWABARA Kazuo
金额:
$4.74万
依托单位:
依托单位国家:
日本
项目类别:
Grant-in-Aid for General Scientific Research (B)
财政年份:
1994
资助国家:
日本
项目状态:
已结题
起止时间:
1994 至 1995

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中文摘要
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英文摘要
1. Twelve new cobalt (III) complexes containing tetradentate phosphine ligands, 5,8-diphenyl-5,8-diphospha-2,11-dithiadodecane (222SPPS) and 5,9-diphenyl-5,9-diphospha-2,12-dithiatridecane (232SPPS). The crystal structures of cisalpha-[CoCl_2{rac (P) -222SPPS}] BF_4 and trans-[CoCl_2{meso (P)-222SPPS}] BF_4 were determined by single crystal X-ray diffraction.2. Bis (dimethyldithiocarbamato) (4,6-diphenyl-4,6-diphosphanonane-1,9-diammonium) cobalt (III) and chloro (4,9-dephenyl-4,9-diphosphadodecane-1,12-diamine) nickel (II) complexes were prepared and the crystal structures were determined by single crystal X-ray diffraction.3. Rh (III), Pd (II), Pd (I) and Fe (II) complexes of various phosphine ligands such as 1,2-or 1,3-diphosphines, a tripod tridentate phosphine, and 8- (dimethylphosphiono) quinoline were prepared and the crystal structures were determined by X-ray analyzes.
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会议论文
T.Suzuki: "Preparation and Characterization of Mononuclear Palladium (II) and Dinuclear Palladium (I) Complexes Containing a New Phosphine-Imine・Type Didentate Ligand,8- (Dimethylphosphino) quinolir" Bull.Chem.Soc.Jpn.68. 1619-1626 (1995)
T.Suzuki:“含有新型膦亚胺·型二齿配体 8-(二甲基膦基)喹啉的单核钯 (II) 和双核钯 (I) 配合物的制备和表征”Bull.Chem.Soc.Jpn.68。 -1626 (1995)
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通讯作者:
K.Kashiwabara, M.Kita, H.Masuda, S.Kurachi, S.Ohba: "Crystal Structures of Cobalt (III)-Methyldiphenyphosphine Complexes. Co (III)-P Bond Lengths and Their Cleavages" Bull.Chem.Soc.Jpn.68. 883-888 (1995)
K.Kashiwabara、M.Kita、H.Masuda、S.Kurachi、S.Ohba:“钴 (III)-甲基二苯膦配合物的晶体结构。Co (III)-P 键长及其裂解”Bull.Chem.Soc。
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通讯作者:
M.Kita: "Crystal Structures of trans- 〔CoCl2 { (CH3) 2PCH2CH2P (CH3) 2} 2〕 ClO4,trans (Cl,Cl) cis (P,P) - 〔CoCl2 {NH2CH2CH2P (CH3) 2} 2〕 PF6 and trans- 〔CoCl2 (NH2CH2CH2NH2) 2〕 NO3" Bull.Chem.Soc.Jpn.67. 2457-2462 (1994)
M.Kita:《反式-〔CoCl2{(CH3)2PCH2CH2P(CH3)2}2〕ClO4,反式(Cl,Cl)顺式(P,P)-〔CoCl2{NH2CH2CH2P(CH3)2}2〕的晶体结构PF6 和反式-[CoCl2 (NH2CH2CH2NH2) 2] NO3" Bull.Chem.Soc.Jpn.67. 2457-2462 (1994)
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K.Kashiwabara: "Synthesis and Crystal Structure of Bis(1,1,1-tris(dimethylphosphinom ethyl)ethane)iron(II)Tetrafluoroborate Dihydrate" Bull.Chem.Soc.Jpn.68. 3453-3457 (1995)
K.Kashiwabara:“双(1,1,1-三(二甲基膦基乙基)乙烷)铁(II)四氟硼酸二水合物的合成和晶体结构”Bull.Chem.Soc.Jpn.68。
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13
    Synthesis of high functional phosphine ligands and their metal complexes
    • 批准号:
      11640562
    • 项目类别:
      Grant-in-Aid for Scientific Research (C)
    • 资助金额:
      $2.3万
    • 财政年份:
      1999
    • 负责人:
      KASHIWABARA Kazuo
    • 依托单位:
    Synthetic studies of hybrid chelate phosphine ligands and their metal complexes
    • 批准号:
      08640709
    • 项目类别:
      Grant-in-Aid for Scientific Research (C)
    • 资助金额:
      $1.34万
    • 财政年份:
      1996
    • 负责人:
      KASHIWABARA Kazuo
    • 依托单位:
    The construction of a high performance spectroelectrochemical system(application to the analyzes of the electronic states of unstable metal lons in solution)
    • 批准号:
      07554061
    • 项目类别:
      Grant-in-Aid for Scientific Research (A)
    • 资助金额:
      $1.41万
    • 财政年份:
      1995
    • 负责人:
      KASHIWABARA Kazuo
    • 依托单位:
    Studies on Syntheses and Reactivities of New Transition Metal Phosphine Complexes
    • 批准号:
      60470046
    • 项目类别:
      Grant-in-Aid for General Scientific Research (B)
    • 资助金额:
      $3.65万
    • 财政年份:
      1985
    • 负责人:
      KASHIWABARA Kazuo
    • 依托单位:
    海外基金