Dicationic diboranes: synthesis and reactivity

双阳离子乙硼烷：合成和反应性

• 批准号: 447235950
• 负责人: Professor Dr. Hans-Jörg Himmel
• 金额: --
• 依托单位: Anorganisch-Chemisches Institut
• 依托单位国家: 德国
• 项目类别: Research Grants
• 资助国家: 德国
• 项目状态: 未结题
• 来源: https://gepris.dfg.de/gepris/projekt/447235950?language=en
• 关键词: Dicationic; diboranes; synthesis; reactivity

While cationic monoboranes were extensively studied and used in a variety of different reactions due to their high Lewis acidity, the chemistry of cationic diboranes is almost unexplored. This project aims at the synthesis of dicationic diboranes with sp3-hybridized as well as with sp2-hybridized boron atoms and the detailed evaluation of their reactivity, e.g. the interesting combination of high Lewis acidity and electron-rich B-B bond. The work in this project profits from the experience with such compounds in my group.

尽管由于高刘易斯酸度，阳离子单泡经过广泛的研究并用于各种不同的反应中，但几乎没有探索阳离子二曲霉的化学。该项目的目的是将Dicaticic Diboranes与Sp3杂交以及SP2杂交硼原子合成，并详细评估其反应性，例如高路易斯酸度和富含电子的B-B键的有趣组合。该项目的工作从我小组中这种化合物的经验中获利。