Establishment of the principle of the design of new opto-electro-fiinctional mataials by the control of the properties of silicon-containing compounds

本研究的目的是建立光电功能材料的设计原则，通过控制含硅化合物的性能，基于精确控制的反应和初级和高级结构的硅-氧键的特征反应。有三个目标。(1)首次研究了基于硅氧键的初级和高级结构与性能控制的封装材料和新型功能材料的设计，即硅氧键形成反应的发展和完善、微孔材料的形成、结构可控的三维倍半硅氧烷的形成、以及利用液晶化合物的不相容性设计新型功能材料。(2)控制硅-硅硼化合物的主特性和共轭特性设计新型功能材料原理的建立 ...更多信息 （3）研究了通过控制有机硅化合物的立体化学结构来开发高性能材料，本研究以作者发现的有机硅化合物的新反应为基础进行了探索。获得了各种有用的结果。其中，通过硅烷和水之间的脱氢反应形成硅氧键和合成新的含正戊烷的聚合物是一个显著的高效和独特的反应。高效率的光致发光材料的开发是另一个独特的结果。光学活性的Sib '阴离子的开发及其在形成有规立构的聚硅氧烷中的用途也是非常有价值的结果。该反应和产物被用于开发高性能材料。此外，还建立了具有可控结构的聚倍半硅氧烷的反应机理。这些化合物被用于制备新型高性能聚硅氧烷聚合物和全息材料，从而很好地实现了本研究的初衷。少

This research was carried out with the aim of the establishment of the principle to design opto-electro-functional materials by the control of the properties of silicon-containing compounds based on the precise control of the reaction and primary and higher order structure of silicon-oxygen bond using the characteristic reactions. Three objects were pursued.(1) Design of package materials and new functional materials based on the control of primary and higher order structure and properties of silicon-oxygen bond was firstly studied, namely development and refinement of the formation reaction of silicon-oxygen bond, formation of micro-porous materials, formation of three dimensional silsesquioxane with well-controlled structure, and usage of the incompatibility of liquid crystalline compounds in designing new functional materials.(2) Establishment of the principle to design new functional materials based on the control of the primary and conjugative characteristics of silicon-silicon bo … More nd, and(3) Development of high performance materials by the control of the stereo-chemical structure were studied.In this research, approach was made based on the newly developed reactions of silicon compounds found by the author. Various useful results were obtained. Among them, formation of silicon-oxygen bond, and the synthesis of new siloxane-containing polymers by the dehydrogenation reaction between silane and water is a notable highly efficient and unique reaction. Development of photo-luminescent material with high efficiency is another unique result. Development of optically active sib,' anion and its use in the formation of stereoregular polysiloxanes is also a highly valuable result. This reaction and the products were used to develop high performance materials. Establishment of the reaction mechanism of the formation of polysilsesquioxane with controlled structure is also a notable result. These compounds were used to create new high performance polysiloxanes polymers and holographic materials.Thus, the original aims of this research were well-achieved. Less