Nanoscale Conjugated Ladder Polymers
纳米级共轭梯形聚合物
基本信息
- 批准号:455731873
- 负责人:
- 金额:--
- 依托单位:
- 依托单位国家:德国
- 项目类别:Research Grants
- 财政年份:
- 资助国家:德国
- 起止时间:
- 项目状态:未结题
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项目摘要
We will synthesize, characterize and investigate the properties of nanoscale conjugated ladder polymers with rungs based on polycyclic heteroaromatics and two or three strands (termed “side rails” or “legs”) based on arylene-ethynylene-butadiynylenes, and their respective defined linear oligomers. The compounds will be equipped with flexible side chains to guarantee their solution processability. The ladder structures are expected to be rather rigid and should exhibit interesting optical properties. They will be made by homo-polymerization of bisacetylenes (Glaser-coupling) that contain additionally two protected terminal acetylenes. After formation and end-capping of the first strand, deprotection of the remaining acetylenes allows an intramolecular zipping reaction to form the ladder structure, which is then finalized with a second end-capping reaction. The polycyclic heteroaromatic “rungs” of the ladder guarantee on the one hand the stiffness of the polymer and on the other hand, the rungs are readily accessible by a reliable amine-ketone condensation. We will investigate two different polycyclic heteroaromatic rungs that lead to distances between the ladder strands of 12 Å (using diquinoxal pyrene) and 7 Å (using phenanthrazine), respectively. The polymers are end-capped so that they do not contain free acetylenic groups. The endcap can be varied widely. We will also investigate new ladder-type endcaps that allow an intramolecular second end-capping. This will overcome the need for sensitive optimization of the zipping reaction which was necessary so far to obtain structures as free of defects as possible. We will prepare ladders with two strands and also with three strands, which are expected to be even stiffer. For all series of compounds, we will synthesize, characterize (NMR, MS, UV/Vis) and investigate (fluorescence, STM in collaboration with Dr. S.-S. Jester (UNiv. Bonn)) the polymers as well as defined oligomers. We will carry out detailed spectroscopic experiments (on the bulk and single-molecule level) as well as molecular dynamic simulations in collaboration with Prof. Grimme (Univ. Bonn) and Prof. Horinek (Univ. Regensburg) which will allow us to obtain a clear picture of the structure-property relationships with respect to the molecules’ structural, conformational and optical properties.
我们将合成、表征和研究纳米级共轭阶梯聚合物的性质,该聚合物具有基于多环杂芳烃的阶梯和基于芳烯-乙烯-丁二乙烯的两条或三条链(称为“侧轨”或“腿”),以及它们各自定义的线性低聚物。该化合物将配备柔性侧链,以保证其溶液可加工性。梯子结构预计是相当刚性的,应该表现出有趣的光学性质。它们将由含有另外两个保护末端乙炔的双乙炔(glaser偶联)的均聚而成。在第一链的形成和末端覆盖之后,剩余的乙炔的去保护允许分子内的压缩反应形成阶梯结构,然后通过第二个末端覆盖反应完成。阶梯的多环杂芳“梯级”一方面保证了聚合物的刚度,另一方面,这些梯级很容易通过可靠的胺酮缩合得到。我们将研究两种不同的多环杂芳阶梯,分别导致12 Å(使用双喹诺二芘)和7 Å(使用非那嗪)的阶梯链之间的距离。这些聚合物是端盖的,所以它们不含有游离的乙基。端帽可以有很大的变化。我们还将研究允许分子内第二端盖的新型阶梯型端盖。这将克服对压缩反应的敏感优化的需要,这是迄今为止获得尽可能无缺陷的结构所必需的。我们将准备两股和三股的梯子,预计会更硬。对于所有系列的化合物,我们将与s - s博士合作合成,表征(NMR, MS, UV/Vis)和研究(荧光,STM)。Jester (UNiv. Bonn))的聚合物以及定义的低聚物。我们将与Grimme教授(波恩大学)和Horinek教授(雷根斯堡大学)合作进行详细的光谱实验(在体和单分子水平上)以及分子动力学模拟,这将使我们能够获得关于分子结构,构象和光学性质的结构-性质关系的清晰图像。
项目成果
期刊论文数量(0)
专著数量(0)
科研奖励数量(0)
会议论文数量(0)
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Professor Dr. Sigurd Höger其他文献
Professor Dr. Sigurd Höger的其他文献
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