THE FORMATION AND APPLICATION OF NOVEL MICROPOROUS COMPLEXES

新型微孔复合物的形成及应用

• 批准号: 10554041
• 负责人: MORI Wasuke
• 金额: $ 9.41万
• 依托单位: KANAGAWA UNIVERSITY
• 依托单位国家: 日本
• 项目类别: Grant-in-Aid for Scientific Research (B).
• 财政年份: 1998
• 资助国家: 日本
• 起止时间: 1998 至 2000
• 项目状态: 已结题
• 来源: https://kaken.nii.ac.jp/en/grant/KAKENHI-PROJECT-10554041/
• 关键词: gas occlusion; microporous substance; trasition-metal dicarboxylates; ジカルボン酸錯体; 細孔; マイクロポアー物質; 気体吸蔵; 気体貯蔵; ジカルボン酸銅(II); 工業的利用

The dinuclear transition-metal dicarboxylates (Cu(II), Mo(II), Ru(II,III) ) reversibly occlude a large amount of gases such as N_2, 0_2, Ar, and CH_4. It was concluded that the gas molecules are occluded in uniform micropores constracted by transition-metal complexes. The complexes are useful adsorbent for storing gases, and may be useful catalyst for chemical reactions.

双核过渡金属二羧酸盐（Cu（II），Mo（II），Ru（II，III））可逆地吸留大量的气体如N_2，O_2，Ar和CH_4。结果表明，在过渡金属配合物的作用下，气体分子被封闭在均匀的微孔中。该配合物是用于储存气体的有用吸附剂，并且可以是用于化学反应的有用催化剂。

项目成果

M.Tanaka,K.Mashima,M.Nishino,S.Takeda,W.Mori,K.Tani,K.Yamaguchi,and A.Nakamura: "Unique Axial interaction of a Quadruply-Bonded Cr(II)-Cr(II) with Two Pt(II) Atoms in the Linearly Aligned Pt-Cr-Cr-Pt Supported by Four 6-Diphenylphosphino-2-pyridinate Liga

M.Tanaka、K.Mashima、M.Nishino、S.Takeda、W.Mori、K.Tani、K.Yamaguchi 和 A.Nakamura：“四键 Cr(II)-Cr(II) 的独特轴向相互作用

M.Hirotsu, M.Kojima, W.Mari, and Y.Yoshikawa: "Steric control of polynuclear manganese complexes by the use of tripodal tetradentate ligand"Bull.Chem.Soc.Japan.. 71. 2873-2884 (1998)

M.Hirotsu、M.Kojima、W.Mari 和 Y.Yoshikawa：“使用三齿四齿配体对多核锰配合物进行空间控制”Bull.Chem.Soc.Japan.. 71. 2873-2884 (1998)

W.Mori, H.Hoshino, K.Horikawa, Y.Nishimoto, and S.Takamizawa: "Synthesis and gas occlusion of rhodium (II) benzoate bridged by pyrazine derivatives"Mol.Cryst.Liq.Cryst.. 342. 193-198 (2000)

W.Mori、H.Hoshino、K.Horikawa、Y.Nishimoto 和 S.Takamizawa：“吡嗪衍生物桥接的苯甲酸铑 (II) 的合成和气体吸留”Mol.Cryst.Liq.Cryst.. 342. 193-

S.Emori, K.Obata, and W.Mori: "Magnetic characterization of di-μ-hydroxobis (ethylenediamine-N, N-diacetato) dichromium (III). Magneto-structural corrilations in hydroxo-bridged chromium (III) complexes"ITE Letters on Batteries, New Technologies & Medicin

S. Emori、K. Obata 和 W. Mori：“二-μ-羟基双（乙二胺-N，N-二乙酸）二铬 (III) 的磁性表征。羟基桥接铬 (III) 配合物中的磁结构相关性” ITE 关于电池、新技术和医学的信件

W. Mori, H. Hoshino, K. Horikawa, Y. Nishimoto, and A. Takamizawa: "Synthesis and Gas Occlusion of Rhodium(II) Benzoate Bridged by Nitrogen donor Ligands"Molecular Crystals and Liquid Crystals. (in press).

W. Mori、H. Hoshino、K. Horikawa、Y. Nishimoto 和 A. Takamizawa：“氮供体配体桥接的苯甲酸铑 (II) 的合成和气体吸留”分子晶体和液晶。