Development of nanoporous metal coordination compounds for resolution of environment and energy issues

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Porous complexes which we found have been extensively studied in recent years because of their intriguing structures and, more importantly, for their potential applications in gas storage, separation, and catalysis. In this project, we have synthesized the novel porous complexes and evaluated hydrogen adsorption properties and the hydrogen production-catalytic activities of the porous complexes in order to construct a clean energy system. The hydrogen adsorption properties depended upon the node-metals, and the porous complexes having small pore size showed a highly hydrogen-adsorption capability. In the Ru- and Rh-based porous complexes showed a hydrogen production-catalytic activity under the existing co-catalysts.