High Efficiency Energy Storage Using Tailor-made Carbon Gels
High Efficiency Energy Storage Using Tailor-made Carbon Gels
批准号:
14350416
负责人:
TAMON Hajime
金额:
$9.6万
依托单位:
依托单位国家:
日本
项目类别:
Grant-in-Aid for Scientific Research (B)
财政年份:
2002
资助国家:
日本
项目状态:
已结题
起止时间:
2002 至 2003
中文摘要
碳凝胶是一种独特的多孔碳,具有很高的结构可控性。因此,它们可用于需要具有可控多孔结构的碳的各种应用。本项目首先建立一种精确控制碳凝胶结构的方法,然后将这种结构控制的碳凝胶实际应用于锂离子电池、电双层电容器、甲烷储存容器等储能应用,实现高存储效率。我们用非常简单的方法成功地独立控制了碳凝胶的纳、微、毫米级结构。因此,我们使用开发的结构控制方法,制备了结构调整以最大化其储能能力的碳。通过将获得的碳应用于各种储能系统,我们实现了极高的存储容量。例如,我们使用含有硅粉的碳凝胶,以细颗粒的形式合成,使锂离子电池的碳基阳极的存储容量增加了一倍。我们还通过使用以片剂形式合成的定制碳凝胶,将碳基双电层电容器的储能容量提高了一倍
英文摘要
Carbon gels are unique porous carbons, and are known to have a high structure controllability. Therefore they can be used for various applications which require carbons with controlled porous structures. This project was conducted first, to establish, a method for the precise controlling of the structure of carbon gels, and next, to actually apply such structure controlled carbon gels to energy storage applications, such as Li ion batteries, electric double layer capacitors and methane storage vessels and achieve high storage efficiencies.We succeeded in the independent controlling of the nano-, micro-and millimeter level structures of carbon gels by extremely simple methods. Therefore, we used the developed structure controlling methods, and prepared carbons with structures tuned to maximize their energy storage capabilities. We achieved extremely high storage capacities by applying the obtained carbons to various energy storage systems. For example, we doubled the storage capacity of carbon-based anodes for Li ion batteries by using carbon gels including Si powder, which were synthesized in the form of fine particles. We also doubled the energy storage capacities of carbon based electric double layer capacitors, by using tailor made carbon gels synthesized in the form of tablet
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T.Yamamoto et al.: "Interpretation of Structure Formation during the Sol-Gel Transition of a Resorcinol-Formaldehyde Solution by Population Balance"J.Colloid Interface Sci. 264. 532-537 (2003)
T.Yamamoto 等人:“通过群体平衡解释间苯二酚-甲醛溶液的溶胶-凝胶转变过程中的结构形成”J.胶体界面科学。
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通讯作者:
T.Suzuki, T.Hasegawa, S.R.Mukai, H.Tamon: "A Theoretical Study on Storage States of Li Ions in Carbon Anodes of Li Ion Batteries Using Molecular Orbital Calculations"Carbon. 41. 1933-1939 (2003)
T.Suzuki、T.Hasekawa、S.R.Mukai、H.Tamon:“利用分子轨道计算对锂离子电池碳阳极中锂离子存储状态的理论研究”Carbon。
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N.Tonanon et al.: "Influence of Surfactants on Porous Properties of Carbon Cryogels Prepared by Sol-gel Polycondensation of Resorcinol and Formaldehyde"Carbon. 41. 2973-2982 (2003)
N.Tonanon 等人:“表面活性剂对间苯二酚和甲醛溶胶凝胶缩聚制备的碳冷冻凝胶多孔性质的影响”Carbon。
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T.Suzuki et al.: "A Theoretical Study on Storage States of Li Ions in Carbon Anodes of Li Ion Batteries Using Molecular Orbital Calculations"Carbon. 41. 1933-1939 (2003)
T.Suzuki 等人:“利用分子轨道计算对锂离子电池碳阳极中锂离子存储状态的理论研究”Carbon。
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S.R.Mukai et al.: "Reduction of Irreversible Capacities of Amorphous Carbon Materials for Lithium Ion Battery Anodes by Li_2CO_3"Carbon. (in press).
S.R.Mukai 等人:“Li_2CO_3 降低锂离子电池阳极非晶碳材料的不可逆容量”碳。
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共 9 条
Development of high-strength fabrication method of porous particulates by gelation of organic slurry and control method of porous structure
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批准号:26630389
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项目类别:Grant-in-Aid for Challenging Exploratory Research
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资助金额:$2.5万
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财政年份:2014
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负责人:TAMON Hajime
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依托单位:
Synthesis of high-strength tissue invasive bone substitute materials by unidirectional freezing and development of control method of their porous structure
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批准号:24656468
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项目类别:Grant-in-Aid for Challenging Exploratory Research
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资助金额:$2.58万
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财政年份:2012
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负责人:TAMON Hajime
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依托单位:
Development of novel preparation method for monolithic and fibrous zeolites by unidirectional freezing of gels
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批准号:23360342
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项目类别:Grant-in-Aid for Scientific Research (B)
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资助金额:$12.4万
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财政年份:2011
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负责人:TAMON Hajime
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依托单位:
)Preparation of ordered macroporous carbons by using ice crystal growth and control of their hierarchical structure
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批准号:20360349
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项目类别:Grant-in-Aid for Scientific Research (B)
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资助金额:$12.15万
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财政年份:2008
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负责人:TAMON Hajime
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依托单位:
Development of Electrode for Super Capacitor by Using Carbon Gels with Hieratically Controlled Porous Structure
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批准号:18360380
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项目类别:Grant-in-Aid for Scientific Research (B)
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资助金额:$10.64万
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财政年份:2006
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负责人:TAMON Hajime
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依托单位:
Development of Reaction/Separation Devices for Microfabricated Chemical Systems by Ice-Templating
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批准号:16360383
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项目类别:Grant-in-Aid for Scientific Research (B)
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资助金额:$9.79万
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财政年份:2004
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负责人:TAMON Hajime
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依托单位:
Development of Mesoporous Carbon Cryogels with Desired Porous Characteristics by Using Sol-Gel Method and Freeze Drying
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批准号:12650767
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项目类别:Grant-in-Aid for Scientific Research (C)
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资助金额:$2.3万
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财政年份:2000
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负责人:TAMON Hajime
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依托单位:
DESIGN OF ETHYLENE ADSORBENT BASED ON ANALYSIS OF ADSORPTION GEOMETRY USING MOLECULAR ORBITAL CALCULATION
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批准号:10650759
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项目类别:Grant-in-Aid for Scientific Research (C)
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资助金额:$2.05万
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财政年份:1998
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负责人:TAMON Hajime
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依托单位:
DEVELOPMENT OF GAS PURIFICATION TECHNOLOGY USING CORONA DISCHARGE REACTOR WITH FALLING LIQUID FILM
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批准号:05555211
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项目类别:Grant-in-Aid for Developmental Scientific Research (B)
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资助金额:$2.75万
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财政年份:1993
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负责人:TAMON Hajime
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依托单位:
NEW CORRELATION METHOD OF LIQUlD-PHASE ADSORPTION EQUILIBRIUM BY FRONTIER ORBITAL THEORY
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批准号:04650853
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项目类别:Grant-in-Aid for General Scientific Research (C)
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资助金额:$1.28万
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财政年份:1992
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负责人:TAMON Hajime
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依托单位:
海外基金