Submillimeter-wae Investigations of Reaction Intermediates Relevant to Interstellar and Atmospheric Chemistry

与星际和大气化学相关的反应中间体的亚毫米波研究

• 批准号: 13440172
• 负责人: AMANO Takayoshi
• 金额: $ 5.18万
• 依托单位: Ibaraki University
• 依托单位国家: 日本
• 项目类别: Grant-in-Aid for Scientific Research (B)
• 财政年份: 2001
• 资助国家: 日本
• 起止时间: 2001 至 2003
• 项目状态: 已结题
• 来源: https://kaken.nii.ac.jp/en/grant/KAKENHI-PROJECT-13440172/
• 关键词: Submillimeter-wave spectroscopy; Interstellar molecules; Deuterated species; Earth's atmosphere; Molecular ions; Free radicals; サブミリ波; 大気化学; クラスター

During the past several years, out effort was focused on submillimeter-wave spectroscopic studies of free radicals and molecular ions, in particular, of astrophysical and atmospheric chemical interests. Very high-sensitivity, high-precision, and high efficiency of data acquisition of a spectrometer system are the most crucial factors for successful search of free radicals and ions. To achieve this goal, we employed Russian-made backward-wave oscillators as radiation sources. The oscillation frequencies have been stabilized by using a double phase-lock loop. Below major results are summarized and full report already published on these results will attached as Appendices. The collaboration with the JEM/SMILES group has been measured. These projects are also pursued in collaboration with the JPL group.Major achievements obtained during this project term are mainly in the following areas: (1)Spectroscopy of unstable species (2)Identification of reaction intermediates in discharge plasma used for plasma CVD processes. (3Precise pressure broadening measurements of molecules relevant to the Earth's atmospheric chemistry.

在过去几年中，我们的工作重点是自由基和分子离子的亚毫米波光谱研究，特别是天体物理学和大气化学研究。光谱仪系统的高灵敏度、高精度和高效率的数据采集是成功寻找自由基和离子的最关键因素。为了实现这一目标，我们采用俄罗斯制造的返波振荡器作为辐射源。采用双锁相环稳定了振荡频率。下面总结了主要结果，并将这些结果的完整报告作为附录随附。对与正义运动/SMILES小组的合作进行了衡量。这些项目也是与JPL小组合作进行的。在本项目期间取得的主要成果主要在以下几个方面：（1）不稳定物质的光谱学（2）等离子体CVD工艺中放电等离子体中反应中间体的鉴定。（3）与地球大气化学有关的分子的精确压力展宽测量。

项目成果

T.Amano, Z.Zelinger: "Submillimeter-wave Spectroscopy of HNC Produced in an Extended Negative Glow Discharge"J.Mol.Spectrosc. 211. 273-278 (2002)

T.Amano、Z.Zellinger：“在扩展负辉光放电中产生的 HNC 的亚毫米波光谱”J.Mol.Spectrosc。

T.Hirao, T.Amano: "Laboratory Submillimeter-wave Detection of D_2H^+ : A New Probe into Multiple Deuteration?"Astrophys.J.Letters. 597. L85-L87 (2003)

T.Hirao、T.Amano：“D_2H^ 的实验室亚毫米波检测：多重氘化的新探针？”Astrophys.J.Letters。

H.Habara, A.Maeda, T.Amano: "Submillimeter-wave spectrum of the FCO radical."J.Mol.Spectrosc.. 221. 31-37 (2003)

H.Habara、A.Maeda、T.Amano：“FCO 基团的亚毫米波光谱。”J.Mol.Spectrosc.. 221. 31-37 (2003)

T.Hirao, T.Amano: "Precise Laboratory Rest Frequency of a Submillimeter-Wave Line of D_2H^+."The Interstellar Medium in Galaxies(91 Springer Proceedings in Physics). 103-106 (2003)

T.Hirao、T.Amano：“D_2H^ 亚毫米波线的精确实验室静止频率。”星系中的星际介质（91 施普林格物理学报）。

T.Amano, M.M.Yamada: "Pressure Broadening Measurements at Ibaraki; BrO and O_3."Proceedings of International Workshop on Critical Evaluation of mm/sub-mm-wave Spectroscopic Data for Atmospheric Observations. 28-31 (2004)

T.Amano、M.M.Yamada：“茨城的压力展宽测量；BrO 和 O_3”。大气观测毫米/亚毫米波光谱数据批判性评估国际研讨会论文集。