Structure and Dynamics of Ions and Free Radicals : Investigations by Submillimeter-wave Spectroscopy

离子和自由基的结构和动力学：亚毫米波光谱研究

• 批准号: 16350004
• 负责人: AMANO Takayoshi
• 金额: $ 5.25万
• 依托单位: Ibaraki University
• 依托单位国家: 日本
• 项目类别: Grant-in-Aid for Scientific Research (B)
• 财政年份: 2004
• 资助国家: 日本
• 起止时间: 2004 至 2005
• 项目状态: 已结题
• 来源: https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-16350004/
• 关键词: Submillimeter-wave; Interstellar molecule; Deuterated species; Atmosnheric chemistry; Ions; Free radicals; サブミリ波; 星間化学

This project was planned to pursue a further development of our on-going project on high-resolution spectroscopic investigation of molecular ions and free radicals which had been our main research objectives in the past several years. A major workhorse to promote our investigation is a submillimeter-wave spectrometer system. One such machine had been constructed on the basis of the past several years of research activities. The spectrometer covers the frequency range of 270-860 GHz with three back-ward wave oscillators. During the period of this research project, another similar submillimeter system has been completed. It utilizes a millimeter-wave frequency synthesizer as a local oscillator opposed to a millimeter-wave Gunn oscillator used in the old system. In addition, Fourier transform visible spectroscopy of the Swan system of C_2 and a visible system of C_3 has been carried out as a part of the collaboration with Professor Bernath at University of Waterloo by using a Bruker Fourier transform spectrometer.Major achievements obtained during this project term are mainly in the following areas.(1) Spectroscopy of molecular ions. (2) Extended investigation of the Swan band system of C_2. (3) Precise pressure broadening measurements of molecules relevant to the Earth's atmospheric chemistry.

这个项目是为了进一步发展我们正在进行的分子离子和自由基的高分辨率光谱研究项目，这是我们过去几年的主要研究目标。促进我们研究的一个主要工具是亚毫米波光谱仪系统。在过去几年研究活动的基础上，已经建造了一台这样的机器。该谱仪具有三个返波振荡器，覆盖270-860 GHz的频率范围。在本课题研究期间，又完成了一个类似的亚毫米波系统。它利用毫米波频率合成器作为本机振荡器，而不是旧系统中使用的毫米波古恩振荡器。此外，作为与滑铁卢大学Bernath教授合作的一部分，我们利用布鲁克傅里叶变换光谱仪对C_2的Swan系统和C_3的可见光系统进行了傅里叶变换可见光谱研究。(1)分子离子光谱学。(2)C_2分子天鹅带系统的扩展研究(3)与地球大气化学有关的分子的精确压力展宽测量。

项目成果

Pressure broadening measurement of submillimeter-wave lines of 0_3

0_3亚毫米波谱线的压力展宽测量

• 发表时间: 2005
• 期刊: Journal of Quantitative Spectroscopy & Radiative Transfer 95
• 作者: M.M.Yamada;T.Amano
• 通讯作者: T.Amano

Pressure broadening measurement of submillimeter-wave lines of O_3

O_3亚毫米波谱线的压力展宽测量

• 发表时间: 2005
• 期刊: Journal of Quantitative Spectroscopy & Radiative Transfer 95
• 作者: M.M.Yamada;T.Amano
• 通讯作者: T.Amano

Pressure broadening measurement of submillimeter-wave lines of O3

O3亚毫米波谱线的压力展宽测量

• 发表时间: 2005
• 期刊: Journal of Quantitative Spectroscopy & Radiative Transfer (In press)
• 作者: M.M.Yamada;T.Amano
• 通讯作者: T.Amano

Submillimeter-wave lines of H_2D^+ and D_2H^+ as probes into chemistry in cold dark clouds

H_2D^ 和 D_2H^ 的亚毫米波线作为冷乌云中化学的探索

• 发表时间: 2006
• 期刊: Philosophical Transaction of Royal Society of London A (accepted)
• 作者: T.Amano;T.Hirao;K.Hashimoto;T.Amano
• 通讯作者: T.Amano

Submillimeter-wave spectroscopy of HCNH+ and CH3CNH+

• DOI: 10.1016/j.molstruc.2006.02.035
• 发表时间: 2006-08-21
• 期刊: JOURNAL OF MOLECULAR STRUCTURE
• 影响因子: 3.8
• 作者: Amano, T.;Hashimoto, K.;Hirao, T.
• 通讯作者: Hirao, T.