Dynamics Theory of Chemical Reaction

化学反应动力学理论

• 批准号: 04243105
• 负责人: NAKAMURA Hiroki
• 金额: $ 46.34万
• 依托单位: Okazaki National Research Institutes
• 依托单位国家: 日本
• 项目类别: Grant-in-Aid for Scientific Research on Priority Areas
• 财政年份: 1992
• 资助国家: 日本
• 起止时间: 1992 至 1995
• 项目状态: 已结题
• 来源: https://kaken.nii.ac.jp/en/grant/KAKENHI-PROJECT-04243105/
• 关键词: nonadiab.trans.; reaction dynamics; superexcited states; large ampl.motion; laser in duced dynamics; vibvonic interaction; highly excited vibr.; hyperspherical coordinates; レーザー憂起動力学; 波束動力学; 高振動励起状態

Many achievements of were attained in various fields of dynamics.(1) Various applications of newly completed theory of Landau-Zener-Stueckelberg problem (Nakamura).(2) Elucidation of quantum dynamics of atom transfer reactions (Nakamura).(3) Development of a general method for characteristics and dynamics of superexcited states (Nakamura).(4) Development of a general procedure to dissociation reactions (Sakimoto).(5) Development of new semiclassical theory for dynamics such as tunneling and chaos (Takatsuka).(6) Development of a general methodology for laser-molecule interactions (Fujimura).(7) Development and applications of time-dependent method to clarity dynamics such as photo dissociation (Yamashita)

在动力学的各个领域都取得了许多成就。(1)Landau-Zener-Stueckelberg问题（中村）新完成理论的各种应用。(2)原子转移反应的量子动力学解析（中村）。(3)超激发态特性和动力学的一般方法的发展（中村）。(4)开发解离反应的一般程序（Sakimoto）。(5)开发新的半经典理论的动力学，如隧道和混沌（高冢）。(6)激光-分子相互作用一般方法学的发展（藤村）。(7)开发和应用时间相关方法来研究光解离等透明动力学（山下）

项目成果

A.Tachibana: "Vibronic Attractive Interaction for Superconductivity in a Local Model of C_<60>" Chem.Phys.Left.(1992)

A.Tachibana：“C_<60> 局域模型中超导的振动吸引相互作用”Chem.Phys.Left.(1992)

K.Moribayashi: "Hyperspherical Approach to Double-electron Excitation of He by Fast-ion Impact.IV Excitation to the (21,31') and (31,31') Manifolds by Multiply-charged Ion Impact" Phys.Rev.A.

K.Moribayashi：“通过快离子撞击实现 He 双电子激发的超球方法。通过多电荷离子撞击对 (21,31) 和 (31,31) 流形进行 IV 激发”Phys.Rev.A

J.Z.Tang: "Evidence of an Excited Angular Correlation Mode in High-lying He^-" Phys.Rev.Lett.69. 1633-1635 (1992)

J.Z.Tang：“高地氦中激发角相关模式的证据^-”Phys.Rev.Lett.69。

K.Yamashita: "Calculation on the Rate of the Ion-molecule Reaction C_2H_2^++H_2→C_2H_3+H" J.Chem.Phys.96. 5801-5807 (1992)

K. Yamashita：“离子分子反应速率 C_2H_2^++H_2→C_2H_3+H 的计算”J.Chem.Phys.96 (1992)。

K.Yamashita: "New Ab Initio Potential Surfaces and Three-Dimensional Quantum Dyanmics for Transition State Spectroscopy in Ozone Photodissociation" Chem.Phys.Lett.191. 515-520 (1992)

K.Yamashita：“臭氧光解离过渡态光谱的新从头算势面和三维量子动力学”Chem.Phys.Lett.191。