Accelerated Development of Hybrid nanOporous Compounds for indoor air quality monitoring (ADHOC)

将实施综合高通量合成/吸附/模拟策略，以开发用于选择性吸附四氯乙烯(C2Cl4)的混合纳米孔化合物，C2Cl4是室内空气、土壤和地下水中最普遍的污染物之一，但到目前为止还没有有效的捕获方案。这一史无前例的方法将使一大系列高度稳定的金属有机骨架(MOF)的制备和结构表征伴随着对其C2Cl4吸附性能的快速实验/计算评估，包括亲和力、吸收能力、环保再生能力和对H2O的选择性。将最好的MOF结合到机电式或电式换能器中将被进一步设想为传感应用的概念验证。将涉及在杂化多孔材料合成、结构确定、吸附(CAU)和建模、传感(ICGM)方面协同工作的两个小组。

An integrated high-throughput synthesis/sorption/modelling strategy will be implemented to develop hybrid nanoporous compounds for the selective adsorption of tetrachloroethylene (C2Cl4), one of the most ubiquitous contaminants of indoor air, soil and groundwater, with however no effective capture solution so far. This unprecedented methodology will allow the preparation and structure characterization of a large series of highly stable Metal Organic Frameworks (MOFs) concomitant with a rapid experimental/computational assessment of their C2Cl4 sorption properties in terms of affinity, uptake capacity, eco-friendly regenerative ability and selectivity over H2O. The incorporation of the best MOFs to electromechanical or electrical transductors will be further envisaged as a proof of concept for sensing applications. Two groups working synergistically in hybrid porous materials synthesis, structure determination, sorption (CAU) and modelling, sensing (ICGM) will be involved.