Novel Environmental Catalysts for Practical Applications.

实际应用的新型环境催化剂。

• 批准号: 07242101
• 负责人: IWAMOTO Masakazu
• 金额: $ 47.17万
• 依托单位: HOKKAIDO UNIVERSITY
• 依托单位国家: 日本
• 项目类别: Grant-in-Aid for Scientific Research on Priority Areas
• 财政年份: 1995
• 资助国家: 日本
• 起止时间: 1995 至 1997
• 项目状态: 已结题
• 来源: https://kaken.nii.ac.jp/en/grant/KAKENHI-PROJECT-07242101/
• 关键词: solid catalyst; material catalyst; catalyst design; solid state reaction field; environmental catalyst; unique reaction field; design of active site; 分子ダイナミックス; 環境化学; 深度脱硫; 窒素酸化物; 触媒; ゼオライト; 環境科学; 湿度脱硫

In the research group for hydrodesulfurization, it has been found that a mixture of metal oxide and zeolite was active for the reaction and the active site in Co-Mo catalysts is the Co ion interacted with Mo ions. The researchers for deNOx systems have confirmed the two-stage oxidation of Cu+ ions to CuィイD22+ィエD2 ions depending on the reaction temperature and the degree of ion exchange. The new method in which a reductant is introduced between the oxidation catalyst of NO to NOィイD22ィエD2 and the reduction catalyst of NOx has been evidenced to be very useful to increase the effectiveness of the reductant.

加氢脱硫研究组发现，金属氧化物和分子筛的混合物对反应具有活性，Co-Mo催化剂的活性中心是Co离子和Mo离子的相互作用。脱硝系统的研究人员已经证实，取决于反应温度和离子交换程度，Cu+离子会两阶段氧化为Cu D22+ Cu D2离子。已经证明，在NO至NO的氧化催化剂D22和NOx的还原催化剂D2之间引入还原剂的新方法对于提高还原剂的有效性是非常有用的。

项目成果

M.Yonemitsu et.al.: "Catalytic Epoxidation of Sutilbene and Its Derivatives with tert-Butyl Hydroperoxide on Mn-MCM-41"J.Catal. 178. 207-213 (1998)

M.Yonemitsu 等人：“在 Mn-MCM-41 上用叔丁基过氧化氢催化磺二苯及其衍生物的环氧化”J.Catal。

M. Iwamoto: "Assignment of Nonclassical [Cu(CO)n]+(n=1,2) Complex Ions in Zeolite Cages" Inorg. Chem.35. 1918-1921 (1996)

M. Iwamoto：“沸石笼中非经典 [Cu(CO)n] (n=1,2) 络离子的分配” Inorg。

W.F.Shangguan: "Kinetics of soot-O_2,soot-NO and soot-O_2-NO reactions over spinel-type CuFe_2-O_4 catalyst" Applied Catalysis B:Environmental. 12(2-3). 237-247 (1997)

W.F.Shangguan：“尖晶石型CuFe_2-O_4催化剂上烟灰-O_2、烟灰-NO和烟灰-O_2-NO反应的动力学”应用催化B：环境。

Y.M.Setoguchi: "Rapid Room Temperature Synthesis of Hexagonal Mesoporous Silica Using Inorganic Silicate Sources and Cationic Surfactants under Highly Acidic Conditions" Journal of Porous Materials. 4(2). 129-134 (1997)

Y.M.Setoguchi：“在高酸性条件下使用无机硅酸盐源和阳离子表面活性剂快速室温合成六方介孔二氧化硅”多孔材料杂志。

T. Abe: " Non-Silica-Based Mesostructured Materials, 1. Synthesis of Vanadium Oxide-Based Material" Chem. Mater.7. 1429-1430 (1995)

T. Abe：“非二氧化硅基介孔结构材料，1.氧化钒基材料的合成” Chem。