High-resolution soft-X-ray emission spectroscopy and photoemission spectroscopy of the interface between molecules and electrodes

分子与电极界面的高分辨率软 X 射线发射光谱和光电子能谱

• 批准号: 17069008
• 负责人: SHIN Shik
• 金额: $ 76.29万
• 依托单位: The University of Tokyo
• 依托单位国家: 日本
• 项目类别: Grant-in-Aid for Scientific Research on Priority Areas
• 财政年份: 2005
• 资助国家: 日本
• 起止时间: 2005 至 2009
• 项目状态: 已结题
• 来源: https://kaken.nii.ac.jp/en/grant/KAKENHI-PROJECT-17069008/
• 关键词: シンクロトロン放射光; 光電子分光; 化学結合; 表面吸着; 軟X線吸収; 軟X線発光; 電子状態; 軟X線発行

We developed high-resolution photoemission spectroscopy and time-resolved photoemission spectroscopy using VUV laser and synchrotron radiation with sample preparation chamber where the molecules are adsorbed on the clean metal surface. We studied soft-X-ray-emission spectroscopy on SO_2 molecules on Ni(100) clean surface and these results are analyzed by the theoretical calculation of Tsuneyuki group. Furthermore, We also studied in a single iron(II)-phthalocyanine molecule on an oxidized Cu(110) surface with Kawai-Takagi group.

我们开发了高分辨率的光电子能谱和时间分辨的光电子能谱使用真空紫外激光和同步辐射与样品制备室，其中分子吸附在清洁的金属表面。本文研究了SO_2分子在Ni（100）清洁表面上的软X射线发射光谱，并利用Tsuneyuki群的理论计算对这些结果进行了分析。此外，我们还研究了单个铁酞菁分子在具有Kawai-Takagi基团的Cu（110）表面上的氧化。

项目成果

Anomalous state sandwiched between Fermi liquid and charge ordered Mott-insulating phases of Ti4O7.

• DOI: 10.1103/physrevlett.104.106401
• 发表时间: 2009-02
• 期刊: Physical review letters
• 影响因子: 8.6
• 作者: M. Taguchi;A. Chainani;M. Matsunami;R. Eguchi;Y. Takata;M. Yabashi;K. Tamasaku;Y. Nishino;T. I

Identification of valence electronic states of aqueous acetic acid in acid-base equilibrium using site-selective X-ray emission spectroscopy

• DOI: 10.1039/b910039c
• 发表时间: 2009-01-01
• 期刊: PHYSICAL CHEMISTRY CHEMICAL PHYSICS
• 影响因子: 3.3
• 作者: Horikawa, Yuka;Tokushima, Takashi;Shin, Shik
• 通讯作者: Shin, Shik

Soft X-ray RIXS

软X射线RIXS

• 发表时间: 2007
• 作者: 佐橋一裕;T. Matsushita;M. Hieda;N. Wada;S. Shin
• 通讯作者: S. Shin

Selective observation of the two oxygen atoms at different sites in the carboxyl group (-COOH) of liquid acetic acid

液体乙酸羧基（-COOH）中不同位点的两个氧原子的选择性观察

• 发表时间: 2009
• 期刊: Phys. Chem. Chem. Phys 11
• 作者: T. Tokushima;Y. Horikawa;Y. Harada;O. Takahashi;A. Hiraya;S. Shin
• 通讯作者: S. Shin

Photoemission spectroscopic evidence of gap anisotropy in an f-electron superconductor

f 电子超导体中间隙各向异性的光电光谱证据

• 发表时间: 2005
• 期刊: Phys Rev. Lett. 94
• 作者: T. Kiss;F. Kanetaka;T. Yokoya;T. Shimojima;K. Kanai;S. Shin;Y. Onuki;T. Togashi;C. Zhang;C.T. Chen;S. Watanabe
• 通讯作者: S. Watanabe