High-resolution soft-X-ray emission spectroscopy and photoemission spectroscopy of the interface between molecules and electrodes

我们利用真空紫外激光和同步辐射建立了高分辨率光电子能谱和时间分辨光电子能谱，样品制备室将分子吸附在干净的金属表面。我们研究了SO_2分子在Ni(100)清洁表面的软X射线发射光谱，并用Tsuneyuki群的理论计算进行了分析。此外，我们还研究了含Kawai-Takagi基团的铜(110)氧化表面上的单一铁(II)-酞菁分子。

We developed high-resolution photoemission spectroscopy and time-resolved photoemission spectroscopy using VUV laser and synchrotron radiation with sample preparation chamber where the molecules are adsorbed on the clean metal surface. We studied soft-X-ray-emission spectroscopy on SO_2 molecules on Ni(100) clean surface and these results are analyzed by the theoretical calculation of Tsuneyuki group. Furthermore, We also studied in a single iron(II)-phthalocyanine molecule on an oxidized Cu(110) surface with Kawai-Takagi group.