Functional Transition Metal Complexes with Heavier Element Ligands

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It has been recognized that heavier main-group elements have fundamental difference in electronic properties from their lighter congeners. This viewpoint should be true for coordination chemistry using heavier element ligands as well. In this study, we examined structures and reactivities of group 8-10 metal complexes bearing heavier element ligands. A particular interest has been focused on applications of low-coordinate phosphorus ligands to catalytic reactions and functional molecule synthesis.