Advanced Solid-State Chemistry and Properties of Inorganic Metal Dinitridocarbonates

无机金属二硝基碳酸盐的先进固态化学和性能

• 批准号: 502262946
• 负责人: Professor Dr. Hans-Jürgen Meyer
• 金额: --
• 依托单位: Abteilung für Festkörperchemie und theoretische Anorganische Chemie
• 依托单位国家: 德国
• 项目类别: Research Grants
• 资助国家: 德国
• 项目状态: 未结题
• 来源: https://gepris.dfg.de/gepris/projekt/502262946?language=en
• 关键词: Advanced; Solid; State; Chemistry; Properties

Metal-Dinitridocarbonates have shown to exist in combinations with various metals of the periodic system of elements (PSE). The objective of this research is to develop new compounds, which lead to further understanding of basic science, and are of potential relevance as applied systems. To achieve this goal, we will steadily improve solid-state metathesis (SSM) reactions which can facilitate target-orientated preparations when controlled by (in situ) thermal analysis.In the light of existing compounds, we will focus on three areas that are not yet established: a) complex metal cyanamides (M(NCN)6/nWtal-) as framework compounds, b) metal carbodiimide-carbides (M-(CN2)-(C2)) with potentially interesting electric and magnetic properties, and c) metal carbodiimide-phosphates (M-(CN2)-(PO4)) with optical properties and potential lithium ionic conductivity.

金属-二硝基碳酸酯已被证明与元素周期制（PSE）中的各种金属结合存在。本研究的目的是开发新的化合物，这些化合物可以进一步理解基础科学，并具有潜在的应用价值。为了实现这一目标，我们将稳步改进固态复分解（SSM）反应，该反应可以在（原位）热分析控制下促进靶向制备。鉴于现有的化合物，我们将重点关注三个尚未建立的领域：a)作为框架化合物的复杂金属氰酰胺（M(NCN)6/nWtal-）， b)具有潜在有趣的电和磁性能的金属碳二亚胺-碳化物（M-(CN2)-(C2))，以及c）具有光学性质和潜在锂离子电导率的金属碳二亚胺-磷酸盐(M-(CN2)-(PO4))。