New piperidinones as material platform for reversible polymer chemistries

新型哌啶酮作为可逆聚合物化学的材料平台

• 批准号: 506218062
• 负责人: Professor Dr. Michael Sommer
• 金额: --
• 依托单位: Institut für Chemie
• 依托单位国家: 德国
• 项目类别: Research Grants
• 资助国家: 德国
• 项目状态: 未结题
• 来源: https://gepris.dfg.de/gepris/projekt/506218062?language=en
• 关键词: New; piperidinones; material; platform; reversible

Reversible polymerizations and chemical recycling of polymeric materials is becoming increasingly important for the role of plastics in the actual debate on waste stream management and environmental aspects. Degrading polymeric materials on demand, in a controlled way, with high efficiency and while retaining a high value and purity of degradation products are all key aspects to the future success of closed-loop recycling strategies. This proposal is concerned with the establishment of new and versatile piperidinone-based multifunctional monomers for linear and cross-linked polymer architectures that can be degraded on demand (pH and temperature). Piperidinones show high, aldehyde-like reactivity in addition and condensation reactions with nucleophiles such as alcohols or amines to give hemiacetals/acetals or hemiaminals/aminals, respectively. By tailoring reactivity and functionality of the piperidinone monomer as well as of the nucleophile, structure, architecture and stability of the polymeric product, as well as reversibility of the reaction is highly tunable. The resulting linear and cross-linked polymer architectures with broadly varying properties will be designed for diverse applications such as reversible thermosets, biodegradable high Tg thermoplastics or solid state polyelectrolytes for lithium ion batteries. Fundamental investigations on monomer reactivity will accompany monomer development, polymerization and structural characterization to establish piperidinones as a new material platform.

聚合物材料的可逆聚合和化学回收对于塑料在废物流管理和环境方面的实际辩论中的作用变得越来越重要。以可控的方式按需高效降解聚合物材料，同时保持降解产物的高价值和纯度，是闭环回收策略未来成功的关键。该提案涉及建立新的和通用的基于哌啶酮的多官能单体，用于可以根据需要（pH和温度）降解的线性和交联聚合物结构。在与亲核试剂如醇或胺的加成和缩合反应中，分别得到半缩醛/缩醛或半缩醛胺/缩醛胺，从而显示出高的类环糊精反应性。通过调整哌啶酮单体以及亲核试剂的反应性和官能度，聚合产物的结构、构造和稳定性以及反应的可逆性是高度可调的。所得到的具有广泛不同性质的线性和交联聚合物结构将被设计用于各种应用，例如可逆热固性材料、可生物降解的高Tg热塑性塑料或用于锂离子电池的固态聚电解质。对单体反应性的基础研究将伴随着单体开发、聚合和结构表征，以建立哌啶酮作为新的材料平台。