Gas Phase and Solution Studies of Bioinspired Lanthanide-based Alcohol Dehydrogenation Catalysts (A02)

仿生镧系醇脱氢催化剂的气相和溶液研究（A02）

• 批准号: 517658903
• 金额: --
• 依托单位: Institut für Physikalische Chemie (IPC)
• 依托单位国家: 德国
• 项目类别: Collaborative Research Centres
• 资助国家: 德国
• 项目状态: 未结题
• 来源: https://gepris.dfg.de/gepris/projekt/517658903?language=en
• 关键词: Gas; Phase; Solution; Studies; Bioinspired

The aim of the project is inspired by the recently discovered lanthanide-mediated biocatalysis related to methanol dehydrogenases (MDH). Our comprehensive approach to gain detailed understanding of the structural and mechanistic intricacies will entail the preparation of new tailor-made structural and functional model systems and the correlation of their structural and catalytic properties with detailed gas-phase and condensed-phase measurements of key parameters for catalysis (e.g., by mass spectrometry combined with ion mobility and photo- as well as collision-induced dissociation, gas phase ion chemistry, paramagnetic NMR, time-resolved luminescence and quantum chemical calculations).

该项目的目的是受到最近发现的与甲醇脱氢酶（MDH）相关的镧系元素介导的生物催化的启发。我们全面的方法来详细了解结构和机理的复杂性，将需要准备新的定制结构和功能模型系统，以及它们的结构和催化性能与催化关键参数的详细气相和冷凝相测量的相关性（例如，通过与离子迁移率和光以及碰撞诱导解离、气相离子化学、顺磁NMR、时间分辨发光和量子化学计算相结合的质谱法）。