Ditopic receptors for the cooperative binding of cations and anions

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This project is concerned with the design, synthesis and investigation of new receptor molecules that are capable of simultaneously binding metal cations and anions in a cooperative fashion. The new systems are based on a macrocyclic platform which acts as the metal binding site together with side-arms incorporating functional groups that are designed to cooperatively interact with a suitable anion. Potential applications exist for this category of ditopic receptors in mineral processing where the ability to extract a metal as its metal salt may lead to more efficient solvent extraction processes.