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Studies on the Synthesis of Physiological Active Terpenes and Development of New Synthetic Methods

Studies on the Synthesis of Physiological Active Terpenes and Development of New Synthetic Methods
生理活性萜烯的合成研究及新合成方法的开发
批准号:
62570954
负责人:
YAMAKAWA Koji
金额:
$1.73万
依托单位:
依托单位国家:
日本
项目类别:
Grant-in-Aid for General Scientific Research (C)
财政年份:
1987
资助国家:
日本
项目状态:
已结题
起止时间:
1987 至 1989

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中文摘要
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英文摘要
1.Synthesis of the Physiological Active Terpenes. (1)Synthesis of Eudesman-alpha-methylene-6,12-olide and -8,12-olide by Intra molecular Cycization of Allylic Silylated Aldehydes. (2)Synthetic Method of alpha-Methylene-gamma-lactones Fused to Medium and Large Membered Rings by Intramolecular Cyclization of Formylated Allylhalide (3)Synthesis of Physiological Active Eremophilanes: Cinalyratol Acetate, Aristol-9-en-3-ol and Debneyol.2.Studies on the Microbial Transformations of alpha-Santonin and 11-Dehydro- alpha-santonin. (1)Microbial Hydroxylation of Santonin by Asoeriaus niger. (2)Microbial Hydroxylation of 11- Dehydrosantonin by Asperigus niger.3. alpha,beta-Epoxy Sulfoxides as Useful Intermediates in Organic Synthesis. (1)A Novel Synthesis of alpha-Substituted Carbonyl Compounds, alpha,beta-Unsaturated Ketones, and Esters from Carbonyl Compounds with Carbon Homologation Through alpha,beta-Epoxy Sulfoxides. (2)Magnesium Salt Induced Opening of alpha,beta-Epoxy Sulfoxides. Synthesis of alpha-Chloroketones, alpha-Alkoxyketones. (3)A Novel Synthegis of alpha-Acyl-, 3-Keto-, and Spiro-Cyclic Ethers via Ring-opening alpha,beta-Epoxy Sulfoxides by Hydroxyl Group. (4)A Novel Steroselective Synthesis of (E 1-Acylbutadienes from 1-Chloro alkyl Phenyl Sulfoxides and 4-(Phenylthio)butanal Through alpha,beta-Epoxy Sulfoxides . (5)A Novel Method Annulation Through alpha,beta- Epoxy Sulfoxides with aid of Intramolecular Radical Cyclization. (6)A Novel Synthesis of Aldols and Through the Enolates from alpha,beta-EPOXY Sulfoxides.4.Novel Asymmetric Synthesis Using Optical Active p-Tolylsulfinyl Group as a Chiral Auxiliary. (1)A Novel Synthesis of Chiral Epoxides and Allylic Alcohols. (2)The Practical Procedure of 1-Chloro-p-tolylsulfoxides and a Novel As Asymmetric Synthesis of (+)-Disparule and (-)-trans-Disparule. (3)A Novel Synthesis of (Z)-N-Arylaziridines.
期刊论文(48)
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会议论文
T,Satoh: "A Novel Synthesis of 2-Acyl Cyclic Ethers and 3-Keto Cyclic Ethers Incuding Spiro Cyclic Ethers via Ring-opening α,β-Epoxy Sulfoxides by Hydroxyl Group"" Bull.Chem.Soc.Jpn. 61. 2109-2115 (1988)
T,Satoh:“通过羟基开环 α,β-环氧亚砜新型合成 2-酰基环醚和 3-酮环醚,包括螺环醚”” Bull.Chem.Soc.Jpn. 61. 2109 -2115 (1988)
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T,Satoh: "Stereospecific Desulfination of Sulfinylaziri dines with Ethylmagnesium Bromide:A Novel Synthesis of(Z)-N-Arylaziridines." Tetrahedron Lett. 29. 4093-4096 (1988)
T,Satoh:“用乙基溴化镁对亚磺基氮丙啶进行立体定向脱硫:(Z)-N-芳基氮丙啶的新型合成。”
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通讯作者:
T.Satoh, T.Sato, T.Ohara, K.Yamakawa: "Stereospecific Desulfination of Sulfinlaziridines with Alkyl Metals: A Novel Synthesis Including Asymmetric Synthesis of (Z)-N-Arylaziridines and Some Mechanistic Study." J.Org.Chem., 54, 3973-3978(1989).
T.Satoh、T.Sato、T.Ohara、K.Yamakawa:“用烷基金属对 Sulfinlaziridines 进行立体定向脱硫:一种新颖的合成方法,包括 (Z)-N-Arylaziridines 的不对称合成和一些机理研究。”
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T.Satoh: "Reduction of α-Keto Sulfoxides having Alkyl Group and Chlorine Atom on α-Carbon:A Synthesis of(E)-α,β-Epoxy Sulfoxides." Chem.Pharm.Bill.37. 184-186 (1989)
T. Satoh:“α-碳上具有烷基和氯原子的 α-酮亚砜的还原:(E)-α,β-环氧亚砜的合成。Chem.Pharm.Bill.37”。 )
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48
    HYDROGEN ABSORPTION AND IRON PASSIVE FILM BREAKDOWN IN ALKALINE ENVIRONMENTS
    • 批准号:
      07650850
    • 项目类别:
      Grant-in-Aid for Scientific Research (C)
    • 资助金额:
      $1.22万
    • 财政年份:
      1995
    • 负责人:
      YAMAKAWA Koji
    • 依托单位:
    RESEARCH OF DETECTOR FOR HYDROGEN THROUGH STEEL BY USING ION-CONDUCTED CERAMICS
    • 批准号:
      05453082
    • 项目类别:
      Grant-in-Aid for General Scientific Research (B)
    • 资助金额:
      $4.42万
    • 财政年份:
      1993
    • 负责人:
      YAMAKAWA Koji
    • 依托单位:
    Study on Asymmetric Synthesis and Application to physiological Active Compound
    DEVELOPNENT OF HIGH TEMPERATURE TYPE HYOROGEN DETECTOR BY USING SOITD ELECTROLYTE
    • 批准号:
      03555158
    • 项目类别:
      Grant-in-Aid for Developmental Scientific Research (B)
    • 资助金额:
      $5.38万
    • 财政年份:
      1991
    • 负责人:
      YAMAKAWA Koji
    • 依托单位:
    海外基金