Synthesis of New Functionalized Materials and Development of Their Applications

新型功能化材料的合成及其应用开发

基本信息

  • 批准号:
    01430016
  • 负责人:
  • 金额:
    $ 17.92万
  • 依托单位:
  • 依托单位国家:
    日本
  • 项目类别:
    Grant-in-Aid for General Scientific Research (A)
  • 财政年份:
    1989
  • 资助国家:
    日本
  • 起止时间:
    1989 至 1991
  • 项目状态:
    已结题

项目摘要

In this research project, organic electric conductors, including both low molecular weight chargetransfer complexes derived from new electron donors and acceptors and polyaniline, biodegradable polymers, inorganic nanocomposites tailored by intercalation of organic and/or inorganic substances to layered crystals, and organic silicon compounds containing regularly arranged conjugated pi electron systems were synthesized. Their properties were studied and evaluated as new functionalized materials. A variety of new promising compounds were developed. For example, highly conductive organic compounds, polyaniline with improved conductive and mechanical properties. better biodegradable synthetic polyesters than those of natural origin, inorganic nanocomposites with ionic conduction made from zirconium phosphate by intercalation with ethers and Li salts. and organic silicon polymers with good electric conductivity and photo-resist activity.Further, many new synthetic methods of organic sustrates for functional materials were developed using lanthanoid metal complex catalysts. Mechanism of polymerization generated by radioactive radiation under clathrate condition was studied for the preparation of new type polymers.Reactions of silacycloalkanes induced by light and radioactive radiation were investigated to obtain insights into the relationship between electronic structures and reactivities of organosilicon compounds.
在本研究项目中,合成了有机电导体,包括来自新的电子供体和受体的低分子电荷转移络合物和聚苯胺,可生物降解的聚合物,有机和/或无机物插层到层状晶体中的无机纳米复合材料,以及含有规则排列的共轭pi电子体系的有机硅化合物。作为新型功能化材料,对其性能进行了研究和评价。各种新的有前景的化合物被开发出来。例如,高导电性有机化合物,具有更好的导电性和机械性能的聚苯胺。生物可降解性比天然合成聚酯更好的合成聚酯,通过与醚和锂盐插层制备的具有离子导电性的无机纳米复合材料。以及具有良好导电性和光致抗蚀剂活性的有机硅聚合物。此外,利用稀土金属络合物催化剂开发了许多合成功能材料有机基质的新方法。为了制备新型聚合物,研究了笼状条件下辐射引发聚合的机理,考察了有机硅化合物的电子结构与反应活性之间的关系。

项目成果

期刊论文数量(196)
专著数量(0)
科研奖励数量(0)
会议论文数量(0)
专利数量(0)
S. Yamanaka and M. Hattori: ""Clay Pillared with Ceramic Oxides"" "Chemistry of Microporous Crystals". Kodansha. 89-96 (1990)
S. Yamanaka 和 M. Hattori:“陶瓷氧化物柱状粘土”“微孔晶体化学”。
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    0
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  • 通讯作者:
木谷 皓: "ポリアニリンの導電性及び機械的性質の向上" 電池技術. 4. (1992)
Kitani, Hiroshi:“聚苯胺的导电性和机械性能的改进”电池技术4。(1992)。
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    0
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Masaru Shiotani;塩谷 優: "Radical Ionic Systems(Ed.A.Lund;M.Shiotani):Chapter I.6,Deuterium Labelling Studies of Cation Radicals" Kluwer Academic Publisher, 26 (1991)
Masaru Shiotani;Yu Shiotani:“自由基离子系统(Ed.A.Lund;M.Shiotani):第 I.6 章,阳离子自由基的氘标记研究”Kluwer 学术出版社,26(1991)
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    0
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Masaru Shiotani;塩谷 優: "Handbook of Radiation Chemistry(Ed.Y.Tabata):Chapter III.B.7:ESR Detection of Radicals Trapped in Soild" CRC Press, 6 (1991)
Masaru Shiotani;Yu Shiotani:“辐射化学手册(Ed.Y.Tabata):第 III.B.7 章:固体中捕获的自由基的 ESR 检测”CRC Press,6 (1991)
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    0
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MIYAMOTO Hisakazu(宮本 久一): "Naphthaceno[1,2ーcd:4,5ーc'd']bis[1,2]diselenole as a New Electron Donor" Bulletin of the Chemical Society of Japan. 63. 2441-2443 (1990)
MIYAMOTO Hisakazu:“Naphthaceno[1,2-cd:4,5-cd]bis[1,2]disiselenole as a New Electron Donor”日本化学学会公报 63. 2441 -2443 (1990)。
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    0
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OGURA Fumio其他文献

OGURA Fumio的其他文献

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{{ truncateString('OGURA Fumio', 18)}}的其他基金

SYNTHESES OF NEW ORGANIC ELECTRON DONORS, ACCEPTORS, AND THEIR CHARGE-TRANSFER COMPLEXES, AND STUDIES ON THEIR PROPERTIES
新型有机电子给体、受体及其电荷转移络合物的合成及其性质研究
  • 批准号:
    11640592
  • 财政年份:
    1999
  • 资助金额:
    $ 17.92万
  • 项目类别:
    Grant-in-Aid for Scientific Research (C)
SYNTHESES OF NEW ORGANIC ELECTRON DONORS,ACCEPTORS,AND THEIR CHARGE-TRANSFER COMPLEXES,AND STUDIES ON THEIR PROPERTIES
新型有机电子给体、受体及其电荷转移络合物的合成及其性能研究
  • 批准号:
    09640700
  • 财政年份:
    1997
  • 资助金额:
    $ 17.92万
  • 项目类别:
    Grant-in-Aid for Scientific Research (C)
Synthetic Studies on Organic Electric Conductors Containing Heteroatoms
含杂原子有机导电体的合成研究
  • 批准号:
    05453058
  • 财政年份:
    1993
  • 资助金额:
    $ 17.92万
  • 项目类别:
    Grant-in-Aid for General Scientific Research (B)

相似海外基金

Organic Electron Donors and Acceptors through the Use of Nocovalent Bonding Interaction
通过使用非共价键相互作用的有机电子供体和受体
  • 批准号:
    17K05769
  • 财政年份:
    2017
  • 资助金额:
    $ 17.92万
  • 项目类别:
    Grant-in-Aid for Scientific Research (C)
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