Studies on Synthesis and Practical Evaluation of High Functional Polymeric Materials

高功能高分子材料的合成及实用评价研究

• 批准号: 02045012
• 负责人: MIYATA Seizo
• 金额: $ 3.46万
• 依托单位: Tokyo University of Agriculture and Technology, Faculty of Technology
• 依托单位国家: 日本
• 项目类别: Grant-in-Aid for international Scientific Research
• 财政年份: 1990
• 资助国家: 日本
• 起止时间: 1990 至 1992
• 项目状态: 已结题
• 来源: https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-02045012/
• 关键词: Functional Polymers; Conducting Polymers; Characterization; Polymer Gel; Carbon Fiber; Menbrane Reactor; Natural Rubber; Composite Particle; カ-ボンファイバ-; コ-ルタ-ルピッチ; マイクロカプセル; チチタケ; 高速クロマトグラフィ-; 除放性材料; ポリピロ-ル; 酸化電位; 吸着分離; クロマトグラフィ-

High functional polymeric materials, such as polymers having electric conductivity, separation ability, catalytic activity have been investigated extensively. In this project, preparation and evaluation of new functional polymers have been carried out as a cooperative research between Tokyo University of Agriculture and Technology and Chulalongkorn University of Thailand.Highly conducting polymers were prepared by the oxidation polymerization of pyrrole or thiophene and by adjusting oxidation potential. Polymergels for HPLC were prepared and new HPLC technique for determining composition distribution of copolymers was developed. A new reactors equipped with separation membrane were constructed and its application was discussed. Structure of natural rubber (NR) was studied using various instruments and functionalization of NR was investigated. Hydrogenation mechanism of coal tar for carbon fiber was studied using tritium tracer method. Various combinations of composite particles were prepared employing poly(vinyl chloride) based latices and the product was characterized by SEM, GPC,TLC and so forth.The education system for the student studying natural sciences, especially polymer sciences was discussed between the two groups.

高功能高分子材料，如具有导电性、分离性、催化活性的聚合物，已经得到了广泛的研究。在本项目中，东京农业科技大学与泰国朱拉隆功大学合作开展了新型功能聚合物的制备和评价工作，通过吡咯或噻吩氧化聚合和调节氧化电位制备了高导电聚合物。制备了高效液相色谱聚合物凝胶，建立了测定共聚物组成分布的新的高效液相色谱技术。构建了一种新型的分离膜反应器，并对其应用进行了探讨。采用多种仪器对天然橡胶的结构进行了研究，并对天然橡胶的功能化进行了研究。用氚示踪法研究了煤焦油加氢制取碳纤维的机理。以聚氯乙烯胶乳为基料，制备了不同的复合粒子组合，并用扫描电子显微镜、凝胶渗透色谱仪、薄层层析等手段对产物进行了表征，探讨了两组学生学习自然科学，特别是高分子科学的教育体系。

项目成果

Y.Tanaka: "Rubber and Related Polyprenols" Academic Press Limited, 519-536 (1991)

Y.Tanaka：“橡胶和相关聚戊烯醇”学术出版社有限公司，519-536（1991）

Han Junhi: "Highly Electrically Conducting Polymer Polymer Blends" Synthetic Metals,to be published.

韩俊熙：《高导电聚合物聚合物共混物》合成金属，即将出版。

H.Shono: "Characterization of Pitch-based Carbon Fibers(Part 1)Carbonization Behavior of Stabilized Mesophase Pitch Fibers" Sekiyu Gakkaishi. 34. 510-517 (1991)

H.Shono：“沥青基碳纤维的表征（第 1 部分）稳定中间相沥青纤维的碳化行为”Sekiyu Gakkaishi。

Shinzo Omi, Eisuke Shiiyama, Ken'ich Sakurai, Hiroyuki Yoshimoto, and Mamoru Iso: "Modification of Polyvinyl Chiorede-Vinyl Acetate latex by Seed Emulsion Polymerization" Polymer Inter.30. 271-279 (1993)

Shinzo Omi、Eisuke Shiiyama、Kenich Sakurai、Hiroyuki Yoshimoto 和 Mamoru Iso：“通过种子乳液聚合对聚乙烯基 Chiorede-醋酸乙烯酯乳胶进行改性”Polymer Inter.30。

Shinzo Omi, Eisuke Shiiyama, Kazuyoshi Aita, Masatoshi Matsumoto, Mamoru Iso, st al.: "Synthesis and Fundamental Structural Analysis of Composite PVC Latices" J. Appl. Polym. Sci.41. 631-646 (1990)

Shinzo Omi、Eisuke Shiiyama、Kazuyoshi Aita、Masatoshi Matsumoto、Mamoru Iso 等人：“复合 PVC 胶乳的合成和基本结构分析”J. Appl。