Analysis of Drying Process for Polymer Film

高分子薄膜干燥过程分析

• 批准号: 02650693
• 负责人: SANO Yuji
• 金额: $ 1.47万
• 依托单位: Yamaguchi University
• 依托单位国家: 日本
• 项目类别: Grant-in-Aid for General Scientific Research (C)
• 财政年份: 1990
• 资助国家: 日本
• 起止时间: 1990 至 1991
• 项目状态: 已结题
• 来源: https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-02650693/
• 关键词: Film; Polymide; Polyvinylchloride; Tri-acetate; Mutual Diffusion Coefficient; Drying; Nylon Pellet; Sorption; フィルム; 高分子フイルム; 活量; 高分子溶液; ポリビニルアルコ-ル; ポリイミドフイルム

The drying process of film from polymer solution by heated air are used for the production of various polymer film. Design of the apparatus and determination of optimum operating conditions are carried out only through experiences. In this research, the analyses of the process were performed by two ways : 1) The theoretical simulation by simultaneous numerical solution of the diffusion equation for a slab with the data of equilibrium between vapour pressure of solvent in air and concentration of solvent in film and the mutual diffusion coefficient which were obtained from the sorption experiments. 2) The drying experiments using the batch drying experimental apparatus which can simulate the drying histories of film in commercial apparatus by programmed control of the heating air temperature.(1) Polyvinylchloride-THF system.The batch drying experiments were carried out for both the constant air temperatures and the equivalent time changes of the air temperature in a commercial apparatus … More . The simulation results by the numerical calculations presented the experimental drying histories satisfactorily. The causes of appearance of bubbles in film were 1) boiling of solvent and/or 2) expansion of air included in bottom of film.(2) Polyimide-DMAc system.The drying experiments were carried out for the solutions of DMAc with polyimide polymers of Kapton and Upilex-S. The effect of acceralation of imidization reaction by catalyst on the drying rate was not detected clearly for both polymers. The drying rate for Kapton was larger than that for Upilex-S. The effect of the catalyst on the elastic modulus of the films with a drying histories were not detected clearly. The lower values of elastic modulus was obtained for Kapton.The others investigated by this grant-in-aid are 1) the drying behaviour of 6-Nylon pellet using the batch drying experimental apparatus and 2) the proposal of a novel calculation method of concentration dependent diffusion coefficient on sorption experiment. Less

利用热空气对聚合物溶液进行薄膜干燥的工艺用于生产各种聚合物薄膜。设备的设计和最佳操作条件的确定只能通过经验进行。在本研究中，该过程的分析通过两种方式进行：1）利用吸附实验获得的空气中溶剂蒸气压和膜中溶剂浓度之间的平衡数据以及相互扩散系数，通过联立数值求解板的扩散方程进行理论模拟。 2）使用间歇式干燥实验装置进行干燥实验，该装置可以通过程序控制加热空气温度来模拟商用装置中薄膜的干燥历史。（1）聚氯乙​​烯-THF系统。在商用装置中对恒定空气温度和空气温度的等效时间变化进行间歇式干燥实验……更多。数值计算的模拟结果令人满意地呈现了实验干燥历史。薄膜中出现气泡的原因是1）溶剂沸腾和/或2）薄膜底部空气膨胀。（2）聚酰亚胺-DMAc体系。对DMAc与Kapton和Upilex-S聚酰亚胺聚合物的溶液进行了干燥实验。对于两种聚合物，没有清楚地检测到催化剂加速酰亚胺化反应对干燥速率的影响。 Kapton 的干燥速率大于 Upilex-S。没有清楚地检测到催化剂对具有干燥历史的薄膜的弹性模量的影响。 Kapton 获得了较低的弹性模量值。本次资助的其他研究包括 1) 使用间歇干燥实验装置的 6-尼龙颗粒的干燥行为，以及 2) 吸附实验中浓度依赖性扩散系数的新颖计算方法的建议。较少的

项目成果

佐野 雄二、小渕 茂寿、山本 修一: "高分子フイルム脱着過程Reguear Regimeにおける濃度依存拡散係数の算出方法" 化学工学論文集.

Yuji Sano、Shigehisa Obuchi、Shuichi Yamamoto：“聚合物膜解吸过程的正则机制中浓度依赖性扩散系数的计算方法”化学工程杂志。

佐野 雄二,小渕 茂寿,山本 修一: "高分子フイルム脱着過程Regular Regimeにおける濃度依存性べき乗型近似式による拡散係数の算出方法" 化学工学論文集. 17. 997-1005 (1991)

Yuji Sano、Shigehisa Obuchi、Shuichi Yamamoto：“聚合物膜解吸过程正则状态下使用浓度相关幂律近似公式的扩散系数计算方法”化学工程杂志 17. 997-1005 (1991)。

佐野 雄二他22名: "新しい乾燥技術の実際" 技術情報協会, 1-23 (1991)

Yuji Sano等22人：《新型干燥技术的实用实践》技术信息协会，1-23（1991）

Yuji Sano (22 authors else): "Practice of Modern Drying Technology" Gijyutu Jyoho Kyoukai. Chap. 1. 1-23 (1991)

Yuji Sano（其他 22 位作者）：“现代干燥技术的实践”Gijyutu Jyoho Kyoukai。

Yuji Sano. Sigetosi Kobuchi & Shuichi Yamamoto: "Calculation Method of Mutual Diffusion Coefficient in the Regular Regime of Desorption Process in Polymer Film Based on Approximation of the Power Function for Concentration Dependence of the Diffusion Coef

佐野佑二.