Studies on Advanced Synthesis and Application of Polymers Capable of Material Recognition

具有材料识别能力的聚合物的先进合成及应用研究

• 批准号: 03303010
• 负责人: OKAMOTO Yoshio
• 金额: $ 5.44万
• 依托单位: Nagoya University
• 依托单位国家: 日本
• 项目类别: Grant-in-Aid for Co-operative Research (A)
• 财政年份: 1991
• 资助国家: 日本
• 起止时间: 1991 至 1992
• 项目状态: 已结题
• 来源: https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-03303010/
• 关键词: Molecular recognition; Higher-order structure; Living polymerization; Chiral recognition; Stereo-control; Photofunctional material; Enzymatic polymerization; Polysaccharide; ポルフィリン; 光機能; 糖; オリゴペプチド

Through this research project, interesting and meaningful results were obtained on the following subjects concerning synthesis and application of polymers capable of material recognition. (1) Ability of Photo-recognition (construction of higher-order structure, synthesis of oligonucleotides with prophyrin residue, synthesis of polysilane with difined structure); (2) Ability of Molecular Recognition (molecular recognition of polymers with nucleosides and nucleotides, synthesis of polymers with well-difined structure by living anionic polymerization and living cationic polymerization); (3) Ability of Chiral Recognition (enantioselective synthesis of cyanhidrin with dipeptide complexes, optical resolution by polysaccharide derivative, enzymatic synthesis of cellulose, synthesis of ionopher with saccharide); (4) Ability of Macromolecular Recognition (synthsis of polysaccharides, complex formation by stereoregular polymethacrylates, Synthesis of sequential polymers)

通过这一研究项目，在可识别材料的聚合物的合成和应用方面取得了有趣和有意义的结果。(2)分子识别能力(核苷和核苷酸聚合物的分子识别，通过活性阴离子聚合和活性阳离子聚合合成结构良好的聚合物)；(3)手性识别能力(二肽络合物对映体选择性合成，多糖衍生物的光学拆分，纤维素的酶促合成，离子载体与糖的合成)；(4)大分子识别能力(多糖的合成，规则的聚甲基丙烯酸酯形成络合物，序列聚合物的合成)

项目成果

Y.KAIDA and Y.OKAMOTO: "Optical Resolution by Supercritical Fluid Chromatography Using Polysaccharide Derivatives as Chiral Stationary Phases" Bull.Chem.Soc.Jpn.,. 65. 2285-2288 (1992)

Y.KAIDA 和 Y.OKAMOTO：“使用多糖衍生物作为手性固定相通过超临界流体色谱进行光学拆分”Bull.Chem.Soc.Jpn.,。

M.Marek,Jr.,K.Fukuta,T.Kunitake: "Preparation of Multilayered Film of Ultrathin Poly(tetraallylammonium bromide)Network" Chemistry Letters. 1993. 291-294 (1993)

M.Marek,Jr.、K.Fukuta、T.Kunitake：“超薄聚（四烯丙基溴化铵）网络多层膜的制备”化学快报。

A.Watanage,Y.Nagau,M.Matsuda,M.Suezawa,K.Sumino: "Amorphous Silicon Structure of Heat-Treated Poly(n-propylsilane)Studied by Far-Infrared Sprcrt-scopy" Chem.Phys.Lett.,.

A.Watanage，Y.Nagau，M.Matsuda，M.Suezawa，K.Sumino：“通过远红外光谱研究的热处理聚（正丙基硅烷）的非晶硅结构”Chem.Phys.Lett.，

T.Wada,N.Masumi,Y.Inaki,K.Takemoto.: "Synthesis and interaction studies of watersolble nucleic acid analogs containing serine as a spacer." Nucleic Acids Reseach Symp.,. 27,. 115-116 (1992)

T.Wada、N.Masumi、Y.Inaki、K.Takemoto.：“含有丝氨酸作为间隔基的水溶性核酸类似物的合成和相互作用研究。”

T.Wada,Y.Innaki, and K.Takemoto.: "Synthesis and interaction studies on water soluble nucleic acid analogs:poly-L-lysine derivatives containing thymine and hypoxisantine." J.of Bioactive and Compatible Polymers,. 7. 25-38 (1992)

T.Wada、Y.Innaki 和 K.Takemoto.：“水溶性核酸类似物的合成和相互作用研究：含有胸腺嘧啶和次氧嗪的聚-L-赖氨酸衍生物。”