Studies on Advanced Synthesis and Application of Polymers Capable of Material Recognition

通过该研究项目，在以下关于具有材料识别能力的聚合物的合成和应用的主题上获得了有趣和有意义的结果。(1)光识别能力（2）分子识别能力（含核苷和核苷酸聚合物的分子识别，活性阴离子聚合和活性阳离子聚合合成结构明确的聚合物）;（3）手性识别能力（氰菊酯与二肽复合物的对映选择性合成、多糖衍生物的光学拆分、纤维素的酶促合成、离子亲和素与糖的合成）;（4）大分子识别能力（多糖的分解、通过有规立构的聚甲基丙烯酸酯形成复合物、序列聚合物的合成）

Through this research project, interesting and meaningful results were obtained on the following subjects concerning synthesis and application of polymers capable of material recognition. (1) Ability of Photo-recognition (construction of higher-order structure, synthesis of oligonucleotides with prophyrin residue, synthesis of polysilane with difined structure); (2) Ability of Molecular Recognition (molecular recognition of polymers with nucleosides and nucleotides, synthesis of polymers with well-difined structure by living anionic polymerization and living cationic polymerization); (3) Ability of Chiral Recognition (enantioselective synthesis of cyanhidrin with dipeptide complexes, optical resolution by polysaccharide derivative, enzymatic synthesis of cellulose, synthesis of ionopher with saccharide); (4) Ability of Macromolecular Recognition (synthsis of polysaccharides, complex formation by stereoregular polymethacrylates, Synthesis of sequential polymers)