Molecular Chemistry and Engineering Study on Control and Characterization of Dimensional Functions

1.利用原位拉曼和原位X射线衍射研究了化学反应引起的固液界面和界面结构的变化，观察到锂在碳材料中嵌入/脱嵌过程中阶段和堆积结构的可逆变化。在不同温度下还原预处理的Co/Mo催化剂上NO和CO吸附的FTIR/FTIR结果表明，Co物种与Mo物种相互作用，并封端Mo物种的配位不饱和位点。通过原位扫描隧道显微镜（STM）和原位红外光谱（IR）研究了金属沉积到表面的动力学机制。2.通过分光光度法研究了有机分子、无机分子和碳材料在溶液中的内在功能，以了解分子组装体的空间功能。在极性溶剂中，光照射金属配合物产生的无机自由基优先进行电子转移反应。研究了胶束对铂的分配特性，建立了一种新的痕量铂分析体系。研究了超临界CO2中团簇的形成。3.采用固相反应法、喷雾热分解法和溶液共沉淀法制备了具有优异发光性能和力学性能的层状氧化物化合物。稀土离子激活的化合物表现出很高的发光强度。氧化铈掺杂的氧化锆显示出很高的断裂强度。4.通过电化学和光谱方法研究了双层膜和单层膜中的电子和能量传递机制。电子转移现象占的基础上的隧道机制。通过微电化学测量获得局部膜区域的化学信息。

1.Structural changes of solid-liquid and interfaces induced by chemical reactions were investigated using situ Raman and in situ XRD.Reversible changes in stage and stacking structure were observed on intercalation/deintercalation of lithium in carbon materials. FTIR/DRA results for NO and CO adsorbed on Co/Mo catalysts subjected to reduction pretreatments at several temperatures indicates that the Co species interacts with Mo species and caps the coordinately unsaturated sites of Mo species. The dynamic mechanism of metal deposition and onto surfaces was clarified by in situ STM and in situ IR spectroscopy.2.Intrinsic functions of organic molecules, inorganic molecules, and carbon materials were investigated by spectrophotometric methods to understand the dimensional functions of molecular assemblies in solution. The inorganic radicals generated by light irradiation on metal complexes preferred electron-transfer reactions in polar solvents. The partition properties of micelles were investigated to develop a novel trace analysis system of Pt. The cluster formation in supercritical carbon dioxide was also investigated.3.Layred oxide compounds which have advanced luminescence and mechanical properties were prepared by solid state reactions, spray-pyrolysis method, or coprecipitation in solution. The rare earth ion-activated compounds showed high luminescence intensities. Ceria-doped zirconia showed high fracture strength.4.The electron- and energy-transfer mechanisms in bilayr and monolayr membranes were investigated by electrochemical and spectroscopic methods. The electron-transfer phenomena was accounted for based on a tunneling mechanism. Chemical information in local membrane area was obtained by microelectrochemical measurements.