FUNCTION CREATION OF ELECTROPOLYMERIZED CONDUCTIVE POLYMERS AND THEIR APPLICATION TO HIGH DENSITY SECONDARY BATTERY

电聚合导电聚合物的功能创造及其在高密度二次电池中的应用

• 批准号: 03650664
• 负责人: OSAKA Tetsuya
• 金额: $ 1.22万
• 依托单位: WASEDA UNIVERSITY
• 依托单位国家: 日本
• 项目类别: Grant-in-Aid for General Scientific Research (C)
• 财政年份: 1991
• 资助国家: 日本
• 起止时间: 1991 至 1992
• 项目状态: 已结题
• 来源: https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-03650664/
• 关键词: ELECTROPOLYMERIZED POLYMER; HIGH DENSITY BATTERY; MIM DEVICE; POLYMER BATTERY; ポリマ-電池

WASEDA UNIVERSITYFrom these research on electropolymerized conductive polymers, we summarize the following results.(1) For the application to lithium batteries, the cathode materials composed of polyaniline-polypyrrole multilayer and n-type PPy(polypyrrole)/Pss(polystylene sulfonate) composite were de-signed and it worked for 3V level lithium battery. Moreover, the all solid state lithium battery of Li/PEO-LiC104/PPy was tried to evaluate for high energy density battery.(2) The switching MIM device for LCD driving was proposed to use electropolymerized non-conducting polymer, where MIM is metal(ITO)-insulator(Polymer)-metal(ITO) system. The electropolymetization conditions for making insulator polymers were studied and the polymers were formed until a certain thickness (eg. 0.2 mum) in NaOH, NaHCO or Na CO electrolyte solution. The MIM device showed symmetrical non-linear response and worked for switching device for LCD.(3) The application of the MIM device shown in (2) term to the micro-pH sensor was studied. The insulator polymer responses to very small solution, especially OH pH sensor when added the voltage near the threshold voltage.

从这些电聚合导电聚合物的研究中，我们总结了以下结果。(1)在锂电池应用方面，设计了聚苯胺-聚吡咯多层膜和n型聚吡咯/聚苯乙烯磺酸盐复合正极材料，并用于3V级锂电池。此外，还对Li/PEO-LiC_（104）/PPy的全固态锂电池进行了高能量密度电池评价。(2)提出了一种用于LCD驱动的MIM开关器件，该器件采用电聚合的非导电聚合物，其中MIM是金属（ITO）-绝缘体（Polymer）-金属（ITO）系统。研究了制备绝缘体聚合物的电聚合条件，并将聚合物形成至一定厚度（例如，0.2μ m）在NaOH、NaHCO或NaCO电解质溶液中。MIM器件具有对称的非线性响应，可用于LCD开关器件。(3)研究了（2）项所示MIM器件在微型pH传感器中的应用。绝缘体聚合物响应非常小的溶液，特别是OH pH传感器时，增加的电压接近阈值电压。

项目成果

逢坂 哲彌、門間 聰之: "ポリマー二次電池とその基礎特性評価" 電気化学. 60. 369-375 (1992)

Tetsuya Osaka、Tomoyuki Monma：“聚合物二次电池及其基本表征”电化学 60. 369-375 (1992)。

T.Osaka, T.Fukuda, K.Ouchi, T.Momma: "Conduction Mechanism in Indium Tin Oxide/Electroinactive Polypyrrole/Indium Tin Oxide Sandwich Structures" Thin Solid Films. Vol.215. 200-202 (1992)

T.Osaka、T.Fukuda、K.Ouchi、T.Momma：“氧化铟锡/电化学聚吡咯/氧化铟锡三明治结构的传导机制”固体薄膜。

T.Nakajima: "LCD Driving Characteristics of MIM Diode Using Electropolymerized Polypyrrole Thin Film as an Insulator" Denki Kagaku. 59-12. 1074-1076 (1991)

T.Nakajima：“使用电聚合聚吡咯薄膜作为绝缘体的 MIM 二极管的 LCD 驱动特性”电气化学。

T.Osaka: "Electropolymerization of Electroinactive Polypyrrole Film for a Nonlinear MIM Switching Device" Denki Kagaku. Vol.59-12. 1019-1025 (1991)

T.Osaka：“用于非线性 MIM 开关器件的电惰性聚吡咯薄膜的电聚合”Denki Kagaku。

T.Osaka: "Electrochemical Aspects of Advanced Electronic Materials" Electrochimica Acta. 37. 989-995 (1992)

T.Osaka：“先进电子材料的电化学方面”Electrochimica Acta。