Development of High-performance Organic Electroluminescent Devices Using Amorphous Molecular Materials

利用非晶分子材料开发高性能有机电致发光器件

基本信息

  • 批准号:
    06555261
  • 负责人:
  • 金额:
    $ 3.78万
  • 依托单位:
  • 依托单位国家:
    日本
  • 项目类别:
    Grant-in-Aid for Developmental Scientific Research (B)
  • 财政年份:
    1994
  • 资助国家:
    日本
  • 起止时间:
    1994 至 1995
  • 项目状态:
    已结题

项目摘要

Organic electroluminescent (EL) devices have received attention because of potential application to full color flat panel displays. There have been extensive studies on layred organic EL devices with the aim of achieving high brightness and multicolor emission. However, improvement in the luminance efficiency and durability of devices remains to be solved.We have been studying the synthesis, properties and applications of photo- and electro-active amorphous molecular materials which form readily amorphous glasses above room temperature. It is expected that the amorphous molecular materials function as hole transport materials of organic EL devices since they form stable amorphous film and exhibit relatively high hole drift mobility.In the present study, (1) we have designed and synthesized novel pi-electron starburst molecules and investigated the relationship between molecular structure and the ease of glass formation, glass stability, and glass-transition temperature, (2) we have investigated the hole transport properties of molecular glasses, and (3) we have fabricated layred organic EL devices using amorphous molecular materials as hole transport layr and found that the device exhibit significant durability. In addition, EL devices consisting of double hole transport layrs exhibits a high luminance efficiency. These results provide the novel strategy for developing organic EL devices with high stability and high luminance efficiency using amorphous molecular materials.
有机电致电(EL)设备由于可能应用于全彩色平板显示器而受到关注。已经进行了有关铺设有机设备的广泛研究,目的是实现高亮度和多色发射。然而,设备的亮度效率和耐用性的提高仍有待解决。我们一直在研究光 - 和电活动的无定形分子材料的合成,性质和应用,这些分子材料易于形成室温以上的无定形玻璃。 It is expected that the amorphous molecular materials function as hole transport materials of organic EL devices since they form stable amorphous film and exhibit relatively high hole drift mobility.In the present study, (1) we have designed and synthesized novel pi-electron starburst molecules and investigated the relationship between molecular structure and the ease of glass formation, glass stability, and glass-transition temperature, (2) we have investigated the hole transport properties of分子玻璃和(3)我们使用无定形分子材料作为孔运输Layr制造了铺设有机设备,并发现该设备表现出明显的耐用性。此外,由双孔运输路线组成的EL设备表现出高亮度效率。这些结果为使用无定形分子材料开发具有高稳定性和高亮度效率的有机EL设备提供了新的策略。

项目成果

期刊论文数量(25)
专著数量(0)
科研奖励数量(0)
会议论文数量(0)
专利数量(0)
Y.Kuwabara,H.Ogawa,H.inada,N.noma,Y.Shirota: "Thermally Stable Multilayered Organic Electroluminescent Devices Using Novel Starburst Molecules,4,4′,4″-Tri(N-carbazolyl)-triphenylamine(TCTA)and 4,4′,4″-Tris(3-methylphenylphenylamino)triphycylamine (m-MTDAT
Y.Kuwabara、H.Okawa、H.inada、N.noma、Y.Shirota:“使用新型星爆分子 4,4′,4″-三(N-咔唑基)-三苯胺 (TCTA) 的热稳定多层有机电致发光器件) 和 4,4′,4″-三(3-甲基苯基苯氨基)三乙胺 (m-MTDAT
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Y.Shirota,et al: "Multilayered organic electroluminescent device using a novel starburst molecule,4,4′,4″-tris(3-methylphenylphenylamino)triphenylamine as a hole transport material" Appl.Phys.Lett.65. 807-809 (1994)
Y. Shirota 等人:“使用新型星爆分子 4,4,4”-三(3-甲基苯基苯氨基)三苯胺作为空穴传输材料的多层有机电致发光器件”Appl.Phys.Lett.65。 (1994)
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Y.Shirota, Y.Kuwabara, H.Inada, T.Wakimoto, H.Nakada, Y.Yonemoto, S.Kawami, K.Imai: ""Multilayred organic electroluminescent device using a novel starburst molecule, 4,4', 4''-tris (3-methylphenylamino) triphenylamine sa a hole transport material"" Appl.P
Y.Shirota、Y.Kuwabara、H.Inada、T.Wakimoto、H.Nakada、Y.Yonemoto、S.Kawami、K.Imai:“”使用新型星爆分子的多层有机电致发光器件,4,4, 4
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Y.Kuwabara, H.Ogawa, H.Inada, N.Noma, and Y.Shirota: ""Thermally Stable Multilayred Organic Electroluminescent Devices Using Novel Starburst Molecules, 4,4', 4''-Tri (N-carbazolyl) triphenylamine (TCTA) and 4,4', 4''-Tris (3-methylphenylphenylamino) triph
Y.Kuwabara、H.Okawa、H.Inada、N.Noma 和 Y.Shirota:“使用新型星爆分子 4,4, 4-三(N-咔唑基)三苯胺的热稳定多层有机电致发光器件
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A.Higuchi,Y.Shirota: "Amorphous Molecular Materials : Synthesis and Properties of a Novel Starburst Molecule,4,4',4"-Tri (N-phenoxazinyl) triphenylamine" Mol.Cryst.Liq.Cryst.242. 127-133 (1994)
A.Higuchi,Y.Shirota:“无定形分子材料:新型星爆分子的合成和性能,4,4,4”-三(N-吩恶嗪基)三苯胺”Mol.Cryst.Liq.Cryst.242.127-
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SHIROTA Yasuhiko其他文献

SHIROTA Yasuhiko的其他文献

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{{ truncateString('SHIROTA Yasuhiko', 18)}}的其他基金

Creation of Molecular Glasses and Elucidation of the Relationship between Structures, and Properties and Functions
分子玻璃的创造以及结构、性质和功能之间关系的阐明
  • 批准号:
    08454224
  • 财政年份:
    1996
  • 资助金额:
    $ 3.78万
  • 项目类别:
    Grant-in-Aid for Scientific Research (B)
Development of Highly Performed Organic Display Devices
高性能有机显示器件的开发
  • 批准号:
    08555236
  • 财政年份:
    1996
  • 资助金额:
    $ 3.78万
  • 项目类别:
    Grant-in-Aid for Scientific Research (A)
Synthesis, Properties and Applications of Oligothiophenes with Well-defined Structures and Novel Polymers Containing Pendant Oligothiophenes
结构明确的低聚噻吩及含低聚噻吩侧链的新型聚合物的合成、性能及应用
  • 批准号:
    06453155
  • 财政年份:
    1994
  • 资助金额:
    $ 3.78万
  • 项目类别:
    Grant-in-Aid for General Scientific Research (B)

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Creation of Novel Mechanochromic Amorphous Molecular Materials and Proposal of a Method for Evaluating the Degree of Amorphization
新型力致变色非晶分子材料的创建及非晶化程度评价方法的提出
  • 批准号:
    19K05625
  • 财政年份:
    2019
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    26870424
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    2014
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    Grant-in-Aid for Young Scientists (B)
Science and Function of Organic Amorphous Materials-An Approach from Precise Analysis of Static and Dynamic Structures-
有机非晶材料的科学与功能-静态和动态结构精确分析的方法-
  • 批准号:
    17205018
  • 财政年份:
    2005
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Photoinduced mass transport using amorphous molecular materials
使用无定形分子材料的光诱导质量传输
  • 批准号:
    16550156
  • 财政年份:
    2004
  • 资助金额:
    $ 3.78万
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Surface Relief Grating Formation Using Photochromic Amorphous Molecular Materials
使用光致变色非晶分子材料形成表面浮雕光栅
  • 批准号:
    14540532
  • 财政年份:
    2002
  • 资助金额:
    $ 3.78万
  • 项目类别:
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