New Material Transformation under Unusual Reaction Conditions

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1 High Pressue Reactions : Synthesis of suprampolecular compounds having a novel molecular recognition property, synthesis of aromatic amines via high-pressure promoted nucleophilic aromatic substitution, transformation of nucleic acids by high-pressure promoted enzyme catalysis, cycloaddition reactions of troponoids, several ogranic functional group transformation such as E-Z isomerization and Michael addition reactions of beta-ketoesters.2 Ultrasonic Reactios : Effect of ultrasonics on the solid state organic reactions, ultrasonic reaction activation of fluorouracil derivatives and their use as prodrags, ultrasonic of organic molecules in aqueous media, ultrasonic activation of oxygen and its mechanistic investigation, ultrasonic fluorination of organic molecules, selective transformation of organic compounds in the solid state.3 Flash Vacuum Pyrolysis : Reactivity of carbenes and nitrenes generated at high pressure in vapor phase, synthesis of novel cyclic organosilicon and organogermanium compounds.4 Plasma Chemistry : Selective transformation of organic materials, generation of radical species, surface treatment of functional polymers, structure and reactivity of peroxyl radicals in the solid state.