APPLICATION OF POLYGERMANES TO ORGANIC PHOTOCONDUCTOR

聚锗烷在有机光导体中的应用

• 批准号: 08554024
• 负责人: MOCHIDA Kunio
• 金额: $ 4.16万
• 依托单位: GAKUSHUIN UNIVERSITY
• 依托单位国家: 日本
• 项目类别: Grant-in-Aid for Scientific Research (A)
• 财政年份: 1996
• 资助国家: 日本
• 起止时间: 1996 至 1997
• 项目状态: 已结题
• 来源: https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-08554024/
• 关键词: POLYGERMANES; PHOTOCONDUCTOR; DRIFT MOBILITY; ION RADICAL; PHOTOLYSIS; THERMOLYSIS; パタ-ニング; 光応答性

Syntheses, physical properties, and applications of polygermanes to photoconductor were investigated. Research results are floated by(1) Synthesis of various molecular weight polygermanes which are suited for investigation of band gap, optical and electrical properties.(2) Physical properties of polygermane thin films.(3) Injected carrier drift mobilities measured by the time-of-flight (TOF) technique (10^<-5>-10^<-7> cm^2/V.s).(4) Study of radical cations of oligogermanes and polygermanes by pulse radiolysis technique (two transient absorption bands in the UV-Vis and IR regions).(5) Photochmeical and thermal studies of polygerman ethin films.

研究了聚锗烷的合成、物理性质及其在光电导体中的应用。研究结果主要体现在：（1）合成了适合于带隙、光学和电学性质研究的不同分子量的聚锗烷。(2)聚锗烷薄膜的物理性质。(3)通过飞行时间（TOF）技术测量注入载流子漂移迁移率（10^<-5>-10 ^<-7>cm^2/V.s）。(4)用脉冲辐解技术研究低聚锗烷和多聚锗烷的自由基阳离子（紫外-可见和红外区的两个瞬态吸收带）。(5)聚锗乙烯薄膜的光化学和热学研究。

项目成果

持田 邦夫: "Radical Anions of Oligogermanes. Me(Me_nGe)nME(n=2.3.5.and 10) Generated by Pulse Radiolysis" Chem. Leff.263-264 (1998)

Kunio Mochida：“Oligogermanes 的自由基阴离子。通过脉冲放射分解产生的 Me(Me_nGe)nME(n=2.3.5.and 10)”Chem.263-264 (1998)

持田 邦夫: "Nonlinear Optical Susceptibilities of Oligo-and Polygermanes" Bull. Chem. Soc. Jpn.70. 713-716 (1997)

Kunio Mochida：“寡聚锗烷的非线性光学敏感性”Soc Jpn.713-716（1997）。

Kunio Mochida: "Radical Anions of Oligogermanes, Me (Me_2 Ge)_n Me (n=2,3,5, and 10) Generated by Pulse Radiolysis" Chem Lett.263-264 (1998)

Kunio Mochida：“脉冲放射分解产生的寡锗烷自由基阴离子，Me (Me_2 Ge)_n Me (n=2,3,5, and 10)” Chem Lett.263-264 (1998)

持田邦夫: "Micropattern of GeO_2 1GeC Lines Prepared by UV-Irradiation and Heat Treatment of Polygermane Copolymers of Methylphenylgermylene/Phenylgermylene Unit" J.Applied Organomet.Chem.11. 949-955 (1997)

Kunio Mochida：“通过紫外线照射和热处理甲基苯基甲锗烷/苯基甲锗烷单元制备的 GeO_2 1GeC 线的微图案”J.Applied Organomet.Chem.11 (1997)。

持田 邦夫: "Micropattern of GeO_2/GeC Lines Prepared by UV-Irradiation and Heat Treatment of Polygermanes Copoly mers of Methylohenyl germylene/Phenylgermylene unit" J. Applied. Organomet. Chem.11. 949-955 (1997)

Kunio Mochida：“通过紫外辐照和热处理甲基苯基甲锗烷基/苯基甲锗烷基单元制备的 GeO_2/GeC 线的微图案”J. Applied Chem. 949-955。